[N-(2-Hydroxyethyl)ethylenediamine-κ3N,N′,O]-cis-bis(isothiocyanato-κN)-copper(II)

被引：10
|
作者：
Pasaoglu, H [1 ]
Karadag, A
Tezcan, F
Büyükgüngör, O
机构：
[1] Ondokuz Mayis Univ, Dept Phys, Fac Arts & Sci, TR-55139 Kurupelit, Turkey
[2] Gaziosmanpasa Univ, Dept Chem, Fac Arts & Sci, TR-60250 Tokat, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270104033803
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the novel transition metal isothiocyanate complex of N-(2-hydroxyethyl)ethylenediamine (hydet-en) with copper, [Cu(NCS)(2)(C4H12N2O)], the Cu atom lies in a distorted square-pyramidal environment, coordinated by four N atoms in the basal plane and an apical O atom. The hydet-en ligand is N,N,O-tridentate, in contrast to the disposition in previously studied complexes, while the isothiocyanate ions act as N-atom donor ligands. The monomeric units are linked to one another by hydrogen bonds.
引用
收藏
页码：M93 / M94
页数：2
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