[N-(2-Hydroxyethyl)ethylenediamine-κ3N,N′,O]-cis-bis(isothiocyanato-κN)-copper(II)

被引：10

作者：

Pasaoglu, H ^{[1
]}

Karadag, A

Tezcan, F

Büyükgüngör, O

机构：

[1] Ondokuz Mayis Univ, Dept Phys, Fac Arts & Sci, TR-55139 Kurupelit, Turkey

[2] Gaziosmanpasa Univ, Dept Chem, Fac Arts & Sci, TR-60250 Tokat, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷

关键词：

D O I：

10.1107/S0108270104033803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the novel transition metal isothiocyanate complex of N-(2-hydroxyethyl)ethylenediamine (hydet-en) with copper, [Cu(NCS)(2)(C4H12N2O)], the Cu atom lies in a distorted square-pyramidal environment, coordinated by four N atoms in the basal plane and an apical O atom. The hydet-en ligand is N,N,O-tridentate, in contrast to the disposition in previously studied complexes, while the isothiocyanate ions act as N-atom donor ligands. The monomeric units are linked to one another by hydrogen bonds.

引用

页码：M93 / M94

页数：2

共 50 条

[1] trans-Bis[N-(2-hydroxyethyl)ethylenediamine-κ2N,N′]bis(isothiocyanato-κN)-nickel(II)
Karadag, A
Bulut, A
Büyükgüngör, O
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : M402 - M404
[2] Bis[N-(2-hydroxyethyl)ethylenediamine-κ3N,N′,O]nickel(II) squarate monohydrate
Uçar, I
Bulut, A
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2730 - M2732
[3] POLAROGRAPHIC STUDY OF COMPLEXES FORMED IN ALKALINE SOLUTION BY COPPER(II) ION WITH ETHYLENEDIAMINE, N-(2-HYDROXYETHYL)ETHYLENEDIAMINE, AND N,N'-BIS(2-HYDROXYETHYL)ETHYLENEDAIMINE
HALL, JL
BUM, MB
JOSEPH, E
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1972, 34 (02): : 529 - &
[4] Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II)
Buvaylo, Elena A.
Kokozay, Volodymyr N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1600 - U1108
[5] Bis[N-(2-hydroxyethyl)-β-alaninato]copper(II)
Pestov, AV
Peresypkina, EV
Virovets, AV
Podberezskaya, NV
Yatluk, YG
Skorik, YA
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : M510 - M512
[6] POLAROGRAPHIC STUDY OF COMPLEXES FORMED IN ALKALINE-SOLUTION BY CADMIUM(II) ION WITH ETHYLENEDIAMINE, N-(2-HYDROXYETHYL)ETHYLENEDIAMINE, AND N,N'-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE
HALL, JL
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1976, 68 (02): : 217 - 222
[7] [N-(2-Hydroxyethyl)ethylenediamine]oxalatocopper(II)
Pasaoglu, Huemeyra
Kastas, Goekhan
Yesilel, Okan Z.
Yildirim, M. Hakki
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1337 - U879
[8] CRYSTAL-STRUCTURE OF BIS(N-(2-HYDROXYETHYL)-ETHYLENEDIAMINE)COPPER(II) CHLORIDE
PAJUNEN, A
NASAKKAL.M
SUOMEN KEMISTILEHTI, 1972, 45 (02): : 47 - &
[9] Syntheses and properties of bivalent metal complexes with N-(2-hydroxyethyl)ethylenediamine-N,N′,N′-triacetic acid and the crystal structure of N-(2-hydroxyethyl)ethylenediamine-N,N′,N′-triacetato-copper(II) monohydrate
Akazawa, M
Inomata, Y
Takeuchi, T
Howell, FS
INORGANICA CHIMICA ACTA, 1998, 271 (1-2) : 13 - 18
[10] PREPARATION, INFRARED-SPECTRA, VISIBLE REFLECTANCE SPECTRA, AND MAGNETIC-MOMENTS OF COPPER(II) COMPLEXES OF N,N'-DI(2-HYDROXYETHYL)ETHYLENEDIAMINE, N-(2-HYDROXYETHYL)ETHYLENEDIAMINE, AND N-(HYDROXYPROPYL)ETHYLENEDIAMINE
ZIMMERMA.DN
HALL, JL
INORGANIC CHEMISTRY, 1973, 12 (11) : 2616 - 2620

← 1 2 3 4 5 →