Gold(I) and Palladium(II) thiolato complexes containing water-soluble phosphane ligands

被引：70
作者：
Vergara, Elena
Miranda, Susana
Mohr, Fabian
Cerrada, Elena
Tiekink, Edward R. T.
Romero, Pilar
Mendia, Aránzazu
Laguna, Mariano [1 ]
机构：
[1] Univ Zaragoza, Inst Ciencia Mat Aragon, CSIC, Dept Quim Inorgan, E-5009 Zaragoza, Spain
[2] Univ Burgos, Fac Ciencias, Dept Quim, E-09001 Burgos, Spain
[3] Univ Wuppertal, Fachbereich Anorgan Chem, D-42119 Wuppertal, Germany
[4] Univ Texas, Dept Chem, San Antonio, TX 78249 USA
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 18期
关键词：
phosphatic ligands; palladium; gold; thiolato complexes;
D O I：
10.1002/ejic.200700112
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Water-soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques including 2D NMR experiments, and the complexes [Au(S2CNEt2)(PTA)], trans- [Pd(SC5H4N)(2)(PTA)(2)] and trans-[Pd(SC5H4N)(2)(DAPTA)(2)] were additionally characterised by X-ray crystallography; the latter complex is one of the few structurally characterised DAPTA complexes. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
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页码：2926 / 2933
页数：8
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