High thermally stable polysiloxanes cross-linked with di(alkenyl) functionalized DDSQs exhibiting swelling abilities

被引:3
作者
Mitula, Katarzyna [1 ]
Januszewski, Rafal [2 ]
Duszczak, Julia [1 ]
Rzonsowska, Monika [1 ]
Dudziec, Beata [1 ]
机构
[1] Adam Mickiewicz Univ, Fac Chem, Ctr Adv Technol, Dept Organometall Chem, Uniwersytetu Poznanskiego 8 & 10, PL-61614 Poznan, Poland
[2] Adam Mickiewicz Univ, Fac Chem, Ctr Adv Technol, Dept Chem & Technol Silicon Cpds, Uniwersytetu Poznanskiego 8 & 10, PL-61614 Poznan, Poland
关键词
Double-decker silsesquioxane; Polysiloxane; Hydrosilylation; Cross-linking; Swelling; Thermogravimetry; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; DOUBLE-DECKER SILSESQUIOXANE; POSS DERIVATIVES; PDMS; COPOLYMERS; CAGES; NANOCOMPOSITES; PRECURSORS;
D O I
10.1016/j.eurpolymj.2022.111191
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of unique organic-inorganic hybrid materials varied in the construction of the applied polysiloxanes and di(alkenyl)functionalized double-decker silsesquioxanes was designed, synthesized and fully characterized by spectroscopic methods. The presented synthetic strategy based on hydrosilylation reaction conditions was optimized to ensure complete Si-H consumption along with the avoidance of side-products enabling the formation of materials with high conversion. The obtained results revealed the influence of the type and content of DDSQ in cross-linked polymers structures on their thermal and swelling properties which has not been reported so far. Our studies can lead to the preparation of specific materials with tailored properties.
引用
收藏
页数:12
相关论文
共 96 条
[11]   Highly thermally stable mesoporous Poly(cyanate ester) featuring double-decker-shaped polyhedral silsesquioxane framework [J].
Chen, Wei-Cheng ;
Ahmed, Mahmoud M. M. ;
Wang, Chih-Feng ;
Huang, Chih-Feng ;
Kuo, Shiao-Wei .
POLYMER, 2019, 185
[12]   Hydrophilic Polysiloxane Microspheres and Ceramic SiOC Microspheres Derived from Them [J].
Chojnowski, J. ;
Slomkowski, S. ;
Fortuniak, W. ;
Mizerska, U. ;
Pospiech, P. .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2020, 30 (01) :56-68
[13]   Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes [J].
Cordes, David B. ;
Lickiss, Paul D. ;
Rataboul, Franck .
CHEMICAL REVIEWS, 2010, 110 (04) :2081-2173
[14]   Silsesquioxane-Containing Hybrid Nanomaterials: Fascinating Platforms for Advanced Applications [J].
Dong, Fuping ;
Lu, Liangyu ;
Ha, Chang-Sik .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2019, 220 (03)
[15]   Amine-functionalized POSS as cross-linkers of polysiloxane containing γ-chloropropyl groups for preparing heat-curable silicone rubber [J].
Dong, Fuying ;
Zhao, Peijian ;
Dou, Runtao ;
Feng, Shengyu .
MATERIALS CHEMISTRY AND PHYSICS, 2018, 208 :19-27
[16]   Cage-like silsesquioxanes-based hybrid materials [J].
Du, Yajing ;
Liu, Hongzhi .
DALTON TRANSACTIONS, 2020, 49 (17) :5396-5405
[17]   Double-decker Silsesquioxanes: Current Chemistry and Applications [J].
Dudziec, Beata ;
Marciniec, Bogdan .
CURRENT ORGANIC CHEMISTRY, 2017, 21 (28) :2794-2813
[18]   Double-Decker Silsesquioxanes Self-Assembled in One-Dimensional Coordination Polymeric Nanofibers with Emission Properties [J].
Duszczak, Julia ;
Mitula, Katarzyna ;
Santiago-Portillo, Andrea ;
Soumoy, Loraine ;
Rzonsowska, Monika ;
Januszewski, Rafal ;
Fusaro, Luca ;
Aprile, Carmela ;
Dudziec, Beata .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (19) :22806-22818
[19]   Recent developments and applications of protective silicone coatings: A review of PDMS functional materials [J].
Eduok, Ubong ;
Faye, Omar ;
Szpunar, Jerzy .
PROGRESS IN ORGANIC COATINGS, 2017, 111 :124-163
[20]   Effect of incompletely condensed tri-silanol-phenyl-POSS on the thermal stability of silicone rubber [J].
Gao, Xiaoxiao ;
Liu, Hanchao ;
Wei, Haitao ;
Zheng, Jing ;
Huang, Guangsu .
POLYMER BULLETIN, 2019, 76 (06) :2835-2850