Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)6NH3][B7O10(OH)3]

被引：36
作者：
Yang, Sihai
Li, Guobao [1 ]
Tian, Shujian
Lia, Fuhui
Xiong, Ming
Lin, Jianhua
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China
[2] China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2007年 / 180卷 / 08期
基金：
中国国家自然科学基金;
关键词：
polyborate; heptaborate; solvothermal reaction; structure; space group P2(1)/n; supramolecular;
D O I：
10.1016/j.jssc.2007.05.029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)] (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound I crystallizes in monoclinic system, space group P2(1)/n with a = 8.042(2) angstrom, b = 20.004(4) angstrom, c = 10.103(2) angstrom, and beta = 90.42(3)degrees. The anionic [B7O10(OH)(3)]n(2n-) layers are interlinked via hydrogen bonding to form a 3D supramolecular network containing large channels, in which the templated [H3N(CH2)(6)NH3](2+) cations are located. (C) 2007 Elsevier Inc. All rights reserved.
引用
收藏
页码：2225 / 2232
页数：8
相关论文
共 46 条
  • [21] LARSON AC, 1985, 86748 LAUR
  • [22] LI J, 1995, SPECTROCHIM ACTA A, V51, P519, DOI 10.1016/0584-8539(94)00183-C
  • [23] Novel rare earth polyborates. 2. Syntheses and structures
    Li, LY
    Jin, XL
    Li, GB
    Wang, YX
    Liao, FH
    Yao, GQ
    Lin, JH
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (11) : 2253 - 2260
  • [24] Bismuth borates: One-dimensional borate chains and nonlinear optical properties
    Li, LY
    Li, GB
    Wang, YX
    Liao, FH
    Lin, JH
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (16) : 4174 - 4180
  • [25] Bismuth borates:: Two new polymorphs of BiB3O6
    Li, LY
    Li, GB
    Wang, YX
    Liao, FH
    Lin, JH
    [J]. INORGANIC CHEMISTRY, 2005, 44 (23) : 8243 - 8248
  • [26] (NH3CH2CH2NH3)B6O9(OH)2:: Synthesis and crystal structure of a novel layered borate templated by ethylenediamine
    Li, Min
    Chang, Jiazhong
    Wang, Zhenling
    Shi, Hengzhen
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (11) : 3265 - 3269
  • [27] Crystalline inclusion compounds of urea with oxoboron components. Stabilization of the elusive dihydrogen borate anion in a hydrogen-bonded host lattice
    Li, Q
    Xue, F
    Mak, TCW
    [J]. INORGANIC CHEMISTRY, 1999, 38 (18) : 4142 - 4145
  • [28] A new hydrated cesium heptaborate Cs2[B7O9(OH)5]:: Synthesis and crystal structure
    Liu, ZH
    Li, LQ
    [J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (06) : 1247 - 1249
  • [29] Two new borates containing the first examples of large isolated polyborate anions:: Chain [B7O9(OH)5]2- and ring [B14O20(OH)6]4-
    Liu, ZH
    Li, LQ
    Zhang, WJ
    [J]. INORGANIC CHEMISTRY, 2006, 45 (04) : 1430 - 1432
  • [30] STRUCTURAL STUDIES OF BORACITES - CUBIC PHASE OF CHROMIUM CHLORINE BORACITE, CR3B7O13CL
    NELMES, RJ
    THORNLEY, FR
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1974, 7 (21): : 3855 - 3874
12345