Sensitive and Selective Chromogenic Sensing of Carbon Monoxide by Using Binuclear Rhodium Complexes

被引：91

作者：

Esteban, Julio ^{[1
]}

Vicente Ros-Lis, Jose ^{[1
]}

Martinez-Manez, Ramon ^{[1
]}

Dolores Marcos, M. ^{[1
]}

Moragues, Maria ^{[1
]}

Soto, Juan ^{[1
]}

Sancenon, Felix ^{[1
]}

机构：

[1] Univ Politecn Valencia, Univ Valencia, Inst Reconocimiento Mol & Desarrollo Tecnol, Ctr Mixto Univ Politecn Valencia,Dept Quim, Valencia 46022, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 29期

关键词：

binuclear complexes; carbon monoxide; chromogenic detection; rhodium; sensors; CO; SENSOR; IDENTIFICATION;

D O I：

10.1002/anie.201001344

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) CO-catcher: Carbon monoxide can be detected selectively and sensitively by the binuclear rhodium complex cis-[Rh2-(C 6H4PPh2)2(O2CCH 3)2](HO2CCH3)2. This complex, which contains two cydometalated phosphine ligands, coordinates CO axially and undergoes a color change from violet to orange-yellow (see picture). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4934 / 4937

页数：4

共 23 条

[1]

[Anonymous], ANGEW CHEM

[2] Selective chemisorption of carbon monoxide by organic-inorganic hybrid materials incorporating cobalt(III) corroles as sensing components [J].