Effect of carbon nanotubes irradiation by argon ions on the formation of SnO2-x/MWCNTs composite

被引:24
作者
Nesov, S. N. [1 ]
Korusenko, P. M. [1 ]
Povoroznyuk, S. N. [1 ,2 ]
Bolotov, V. V. [1 ]
Knyazev, E. V. [1 ]
Smirnov, D. A. [3 ,4 ]
机构
[1] Russian Acad Sci, Siberian Branch, Omsk Sci Ctr, Omsk 644040, Russia
[2] Omsk State Tech Univ, Mira Ave 11, Omsk 644050, Russia
[3] St Petersburg State Univ, St Petersburg 198504, Russia
[4] Tech Univ Dresden, Inst Solid State Phys, D-01062 Dresden, Germany
基金
俄罗斯基础研究基金会;
关键词
Argon ions; Irradiation; Functionalization; Composite; Tin oxide; Multi-walled carbon nanotubes; XPS; XANES; X-RAY-ABSORPTION; ELECTRONIC-STRUCTURE; GRAPHENE; NANOSHEETS; OXIDE;
D O I
10.1016/j.nimb.2017.08.040
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Methods of transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and X-ray absorption near edge structure (XANES) were used to investigate the influence of irradiation by argon ions of multi-walled carbon nanotubes (MWCNTs) on the composites SnO2-x/MWCNTs formation. It has been shown that irradiation of the MWCNTs leads to the formation of structural defects and oxygen-containing groups in the walls of carbon nanotubes. The presence of the latest in MWCNTs walls leads to chemical interaction of the tin oxide with the surface of MWCNTs through formation of chemical Sn-O-C bonds at the interfaces "Tin oxide-MWCNTs" at synthesis of the composite by CVD method. It has been established that the crystalline structure of the tin oxide,clusters forming on surface of MWCNTs depends essentially on the defectiveness in the structure of the outer walls of carbon nanotubes. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:222 / 229
页数:8
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