Synthesis and characterization of Lanthanum(III) complexes containing 4,4,4-trifluoro-1-(naphthalen-2yl)butane-1,3-dionate

被引：13
|
作者：
Mautner, Franz A. [1 ]
Bierbaumer, Florian [1 ]
Gyurkac, Marcell [2 ]
Fischer, Roland C. [2 ]
Torvisco, Ana [2 ]
Massoud, Salah S. [3 ]
Vicente, Ramon [4 ]
机构：
[1] Graz Univ Technol, Inst Phys & Theoret Chem, Stremayrgasse 9, A-8010 Graz, Austria
[2] Graz Univ Technol, Inst Anorgan Chem, Stremayrgasse 9, A-8010 Graz, Austria
[3] Univ Louisiana Lafayette, Dept Chem, POB 43700, Lafayette, LA 70504 USA
[4] Univ Barcelona, Dept Quim Inorgan & Organ, Marti I Franques 1-11, E-31321 Barcelona, Spain
来源：
POLYHEDRON | 2020年 / 179卷
关键词：
Lanthanum(III); Crystal structure; Synthesis; beta-diketonate compounds; Hirshfeld surface analysis; INTERMOLECULAR INTERACTIONS; ENERGY-TRANSFER; EUROPIUM(III); LUMINESCENCE; NAPHTHOYLTRIFLUOROACETONE; CYCLOPENTADIENYL; LANTHANIDES; SERIES;
D O I：
10.1016/j.poly.2020.114384
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Seven La(III) complexes with the beta-diketonate anion 4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionato(1-) (ntfa) have been synthesized, namely: [La(ntfa)(3)(MeOH)(3)] (1a), [La(ntfa)(3)(H2O)(2)(EtOH)](EtOH) (1b), [La (ntfa)(3)(bipy)(2)] (2), [La(ntfa)(3)(Me(2)bipy)] (3), [La(ntfa)(3)(terpy)] (4), (NEt4)[La(ntfa)(4)] (5) and [La(ntfa)(4)Na (H2O)(EtOH)(Methyl-beta-naphthylketone)] (6), where bipy = bipyridine, Me(2)bipy = 5,5'-dimethyl-bipyridine, terpy = terpyridine, NEt4+ = tetraethylammonium ion and structurally characterized. The tris-beta-diketonate compounds 1a,b, 2-4 form neutral monomeric complexes with C.N. nine for 1a, 1b and 4, eight for 3, and ten in case of 2. The tetrakis-beta-diketonato complexes 5 and 6 have coordination number eight. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数：8
相关论文
共 50 条
  • [31] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF BIS(DI-MU-ETHOXO-BIS[4,4,4-TRIFLUORO-1-(2-THIENYL)BUTANE-1,3-DIONATO]DICOPPER(II))
    JEZOWSKATRZEBIATOWSKA, B
    OLEJNIK, Z
    LIS, T
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (01): : 251 - 254
  • [32] Synthesis and photoluminescent properties of series ternary lanthanide (Eu(III), Sm(III), Nd(III), Er(III), Yb(III)) complexes containing 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedionate and carbazole-functionalized ligand
    Wu, Jing
    Li, Hong-Yan
    Xu, Qiu-Lei
    Zhu, Yu-Cheng
    Tao, Yun-Mei
    Li, Huan-Rong
    Zheng, You-Xuan
    Zuo, Jing-Lin
    You, Xiao-Zeng
    INORGANICA CHIMICA ACTA, 2010, 363 (11) : 2394 - 2400
  • [33] Synthesis and Luminiescence of Eu (III) Complex Based on 4,4,4-Trifluoro-1-(4′-m-Terphenyl)-1,3-Butanedione and 1, 10-Phenanthroline
    Liu Sheng-gui
    Lin Cheng-you
    Wang Hui-hui
    He Pei
    Gong Meng-lian
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30 (03) : 612 - 615
  • [34] TIME DISCRIMINATION IN THE LASER FLUORIMETRY AND ULTRATRACE DETERMINATION OF EUROPIUM(III) AND SAMARIUM(III) WITH 4,4,4-TRIFLUORO-1-(2-THIENYL)-1,3-BUTANEDIONE
    YAMADA, S
    KANO, K
    OGAWA, T
    ANALYTICA CHIMICA ACTA, 1982, 134 (JAN) : 21 - 29
  • [35] Synthesis of thiophene-containing stabilized phosphorus ylides from 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione, acetylenic esters and triphenylphosphine
    Jafari, Ali
    Ahmadi, Ebrahim
    Ramazani, Ali
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2008, 183 (06) : 1489 - 1495
  • [36] THE LIGAND (E)-[4,4,4-TRIFLUORO-1-(TRIFLUOROMETHYL)-1,3-BIS(TRIMETHYLSILOXY)-2-BUTENYL]DIPHENYLPHOSPHINE
    BEKIARIS, G
    ROSCHENTHALER, GV
    BEHRENS, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 618 (12): : 153 - 157
  • [37] CRYSTAL AND MOLECULAR-STRUCTURE AND MAGNETIC-PROPERTIES OF TRIS[DI-MU-METHOXO-BIS[4,4,4-TRIFLUORO-1-(2-THIENYL)BUTANE-1,3-DIONATO]DICOPPER(II)]
    OLEJNIK, Z
    JEZOWSKATRZEBIATOWSKA, B
    LIS, T
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (01): : 97 - 101
  • [38] Solvent induced 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione Cu(II) complexes: Synthesis, structure, DFT calculation and biocidal activity
    Hema, M. K.
    Karthik, C. S.
    Pampa, K. J.
    Manukumar, H. M.
    Mallu, P.
    Warad, Ismail
    Lokanath, N. K.
    POLYHEDRON, 2019, 168 : 127 - 137
  • [39] Crystal structure of dichloro[4,4,4-trifluoro-1-(2′-thienyl)butane-1,3-dionato]-bis(triphenylphosphine)rhenium(III), [Re(C44H34Cl2F3O2P2S)]
    Sawusch, S
    Schilde, U
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1999, 214 (01): : 81 - 82
  • [40] 3-(2,3-dihydro-1,5-dimethyl-3-oxo-2-phenylpyrazol-4-ylimino)-4,4,4-trifluoro-1-(2-thienyl)butane-1,2-dione
    Wang, JL
    Yu, M
    Su, XM
    Miao, FM
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : O385 - O387
12345