Preparation and characterization of chiral copper 12-metallacrown-4 complexes, inorganic analogues of tetraphenylporphyrinatocopper(II)

被引：45

作者：

Halfen, JA ^{[1
]}

Bodwin, JJ ^{[1
]}

Pecoraro, VL ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期

关键词：

D O I：

10.1021/ic9807386

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral 12-metallacrown-4 complexes can now be obtained in high yield using resolved beta-phenylalanine hydroxamic acids as organic scaffolding. These new copper(II) compounds bear a striking resemblance based on size and shape to Cu(II) tetraphenylporphyrin. This suggests that metallacrowns may be useful alternatives to metalloporphyrins in future applications which require high metal densities and well-defined chiral centers.

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页码：5416 / +

页数：3

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