One Approach to Cyclic Carbonates via a Three-Component Cyclization of Phenacyl Bromide, CO2, and Aldehyde

被引：13

作者：

Yan, Peng ^{[1
]}

Tan, Xueqin ^{[1
]}

Jing, Huanwang ^{[1
]}

Duan, Shuhui ^{[1
]}

Wang, Xiaoxuan ^{[1
]}

Liu, Zhongli ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 08期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC CYCLOADDITION; PROPYLENE-OXIDE; DIOXIDE; EPOXIDES; CONVERSION; CATALYSTS; HALIDES; WATER;

D O I：

10.1021/jo1020294

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A three-component cyclization reaction was designed for synthesizing cyclic carbonates in a single operation from phenacyl bromide, CO2, and aldehyde in the presence of lithium diisopropylamide (LDA). These novel reactions were achieved under extremely mild conditions to generate the target products in moderate to good yields within 10 min.

引用

页码：2459 / 2464

页数：6

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