One Approach to Cyclic Carbonates via a Three-Component Cyclization of Phenacyl Bromide, CO2, and Aldehyde

被引：13

作者：

Yan, Peng ^{[1
]}

Tan, Xueqin ^{[1
]}

Jing, Huanwang ^{[1
]}

Duan, Shuhui ^{[1
]}

Wang, Xiaoxuan ^{[1
]}

Liu, Zhongli ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 08期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC CYCLOADDITION; PROPYLENE-OXIDE; DIOXIDE; EPOXIDES; CONVERSION; CATALYSTS; HALIDES; WATER;

D O I：

10.1021/jo1020294

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A three-component cyclization reaction was designed for synthesizing cyclic carbonates in a single operation from phenacyl bromide, CO2, and aldehyde in the presence of lithium diisopropylamide (LDA). These novel reactions were achieved under extremely mild conditions to generate the target products in moderate to good yields within 10 min.

引用

页码：2459 / 2464

页数：6

共 50 条

[31] Silver Nanoparticles Incorporated Covalent Organic Framework Catalyzed Sustainable Synthesis of Cyclic Carbonates and Oxazolidinones Under Atmospheric CO2 Pressure: A Novel Approach of CO2 Utilization
Mondal, Titu
Sarkar, Priyanka
Islam, Mohammad Shahidul
Dahlous, Kholood A.
Islam, Sk. Manirul
CHEMISTRYSELECT, 2025, 10 (03):
[32] DBU/benzyl bromide: an efficient catalytic system for the chemical fixation of CO2 into cyclic carbonates under metal- and solvent-free conditions
Wang, Lin
Kodama, Koichi
Hirose, Takuji
CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (11) : 3872 - 3877
[33] Direct synthesis of cyclic carbonates from olefins and CO2: Single- or multi-component catalytic systems via epoxide or halohydrin intermediate
Han, Feng
Li, Heng
Zhuang, Hongfeng
Hou, Qin
Yang, Qingfeng
Zhang, Bing
Miao, Chengxia
JOURNAL OF CO2 UTILIZATION, 2021, 53
[34] Effective synthesis of cyclic carbonates from CO2 and epoxides catalyzed by acetylcholine bromide-based deep eutectic solvents
Yang, Xiaoqing
Liu, Zimin
Chen, Peng
Liu, Fei
Zhao, Tianxiang
JOURNAL OF CO2 UTILIZATION, 2022, 58
[35] Ionic liquids tailored and confined by one-step assembly with mesoporous silica for boosting the catalytic conversion of CO2 into cyclic carbonates
Su, Qian
Qi, Yaqiong
Yao, Xiaoqian
Cheng, Weiguo
Dong, Li
Chen, Songsong
Zhang, Suojiang
GREEN CHEMISTRY, 2018, 20 (14) : 3232 - 3241
[36] Conversion of CO2 into cyclic carbonates by a Co(II) metal-organic framework and the improvement of catalytic activity via nanocrystallization
Ji, Xiao-He
Zhu, Ning-Ning
Ma, Jian-Gong
Cheng, Peng
DALTON TRANSACTIONS, 2018, 47 (06) : 1768 - 1771
[37] Rapid CO2 coupling to propargylic alcohols: unlocking the production of α-alkylidene cyclic carbonates via continuous flow
Stiernet, Pierre
Verdin, Alexandre
Frisinger, Maja Stina Svanberg
Grignard, Bruno
Malherbe, Cedric
Yuan, Jiayin
Monbaliu, Jean-Christophe M.
Detrembleur, Christophe
GREEN CHEMISTRY, 2025, 27 (03) : 722 - 730
[38] Highly efficient synthesis of cyclic carbonates via deep eutectic solvents from CO2 at the gas-liquid interface of microdroplet under atmospheric pressure condition
Zheng, Leizhi
Liu, Xiemin
Yang, Guoqiang
Liu, Jia
Jiang, Bowen
Liu, Ying
Li, Xinyao
Hu, Xingbang
Zhang, Zhibing
CHEMICAL ENGINEERING SCIENCE, 2024, 289
[39] Synthesis of benzofuro[2,3-c]pyridines via a one-pot three-component reaction
Hu, Jiaxing
Deng, Zhihong
Zhang, Xueqiong
Zhang, Fanglin
Zheng, Hua
ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (27) : 4885 - 4889
[40] Highly cross-linked bifunctional magnesium porphyrin-imidazolium bromide polymer: Unveiling the key role of co-catalysts proximity for CO2 conversion into cyclic carbonates
Valentino, Laura
Campisciano, Vincenzo
Celis, Chloe
Lemaur, Vincent
Lazzaroni, Roberto
Gruttadauria, Michelangelo
Aprile, Carmela
Giacalone, Francesco
JOURNAL OF CATALYSIS, 2023, 428

← 1 2 3 4 5 →