Kinetics of the CN+OCS reaction

被引：6
|
作者：
Park, J [1 ]
Hershberger, JF [1 ]
机构：
[1] N Dakota State Univ, Dept Chem, Fargo, ND 58105 USA
来源：
CHEMICAL PHYSICS LETTERS | 1998年 / 295卷 / 1-2期
关键词：
D O I：
10.1016/S0009-2614(98)00945-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The CN + OCS reaction was studied using flash photolysis/time-resolved infrared laser spectroscopy. The reaction is fast, with a rate constant of (9.75 +/- 0.5) X 10(-11) cm(3) molecule(-1) s(-1) at 296 K and 2.2 Torr pressure. Detection of CO products indicates that the CO + NCS product channel dominates this reaction, and that the CO is produced vibrationally cold, with > 98% in the vibrational ground state. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码：89 / 94
页数：6
相关论文
共 50 条
  • [31] Kinetics investigation of the hydrogen abstraction reaction between CH3SS and CN radicals
    Liu Yan
    Wang Wenliang
    Liu Zhongwen
    Ren Hongjiang
    Journal of Molecular Modeling, 2016, 22
  • [32] KINETICS OF REACTIONS INVOLVING CN EMISSION .2. REACTION BETWEEN OXYGEN ATOMS AND CYANOGEN
    SETSER, DW
    THRUSH, BA
    PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1965, 288 (1413): : 275 - &
  • [33] Kinetics and Mechanism of the CN plus NCO → NCN plus CO Reaction Studied by Experiment and Theory
    Tzeng, Shiang-Yang
    Chen, Po-Hsueh
    Wang, Niann S.
    Lee, L. C.
    Xu, Z. F.
    Lin, M. C.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (22): : 6314 - 6325
  • [34] Kinetics investigation of the hydrogen abstraction reaction between CH3SS and CN radicals
    Liu Yan
    Wang Wenliang
    Liu Zhongwen
    Ren Hongjiang
    JOURNAL OF MOLECULAR MODELING, 2016, 22 (01) : 1 - 8
  • [35] OCS FORMATION IN THE REACTION OF OH WITH CS2
    JONES, BMR
    BURROWS, JP
    COX, RA
    PENKETT, SA
    CHEMICAL PHYSICS LETTERS, 1982, 88 (04) : 372 - 376
  • [36] THE KINETICS OF [FE(CN)(6)](3-), [FE(CN)(6)](4-)/PT ELECTRODE-REACTION IN CONCENTRATED REACTANT SOLUTIONS
    KISZA, A
    DZIELENDZIAK, J
    KAZMIERCZAK, J
    BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 1994, 42 (02): : 221 - 230
  • [37] KINETICS OF THE [MN(CN)6]4-+E-REVERSIBLE-ARROW[MN(CN)6]5- REACTION AT MERCURY-ELECTRODES
    ORLIK, M
    GALUS, Z
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 366 (1-2): : 97 - 103
  • [38] KINETICS AND MECHANISM OF REACTION BETWEEN AMINOPOLY-CARBOXYLATOMANGANATE(III) COMPLEXES AND CYANIDE IONS - A REINVESTIGATION OF THE MNCYDTA-CN- REACTION
    MISHRA, PK
    PRASAD, S
    NIGAM, PC
    TRANSITION METAL CHEMISTRY, 1990, 15 (06) : 429 - 433
  • [39] Kinetics of reactions of CN with chlorinated methanes
    Samant, Vaishali
    Hershberger, John F.
    CHEMICAL PHYSICS LETTERS, 2008, 460 (1-3) : 64 - 67
  • [40] THE REACTION OF CN RADICALS WITH CYANOACETYLENE
    HALPERN, JB
    MILLER, GE
    OKABE, H
    CHEMICAL PHYSICS LETTERS, 1989, 155 (4-5) : 347 - 350
12345