Kinetics of the CN+OCS reaction

被引：6
|
作者：
Park, J [1 ]
Hershberger, JF [1 ]
机构：
[1] N Dakota State Univ, Dept Chem, Fargo, ND 58105 USA
来源：
CHEMICAL PHYSICS LETTERS | 1998年 / 295卷 / 1-2期
关键词：
D O I：
10.1016/S0009-2614(98)00945-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The CN + OCS reaction was studied using flash photolysis/time-resolved infrared laser spectroscopy. The reaction is fast, with a rate constant of (9.75 +/- 0.5) X 10(-11) cm(3) molecule(-1) s(-1) at 296 K and 2.2 Torr pressure. Detection of CO products indicates that the CO + NCS product channel dominates this reaction, and that the CO is produced vibrationally cold, with > 98% in the vibrational ground state. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码：89 / 94
页数：6
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