Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate

被引:0
作者
Wang, Yan-Zhi [1 ]
Li, Xiao-Kun [1 ]
Yang, Huai-Xia [1 ]
Zhou, Wan [2 ]
Meng, Xiang-Ru [2 ]
机构
[1] Henan Univ Tradit Chinese Med, Coll Pharm, Zhengzhou 450008, Peoples R China
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
LIGANDS; CD(II); ZN(II);
D O I
10.1107/S160053681004331X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Zn(SO4)(C9H8N6)(H2O)(4)]center dot 2H(2)O, the Zn-II ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water molecules in a distorted octahedral geometry. The sulfate tetrahedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19) ratio. In the crystal, adjacent molecules are linked through O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds involving the cation, the anion, and the coordinated and uncoordinated water molecules into a three-dimensional network.
引用
收藏
页码:M1483 / U1376
页数:11
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