Arenedisulfonate-lanthanide supramolecular architectures with phenanthroline as a co-ligand: syntheses and structures

被引：33

作者：

Zhao, Jiong-Peng ^{[1
]}

Hu, Bo-Wen ^{[1
]}

Liu, Fu-Chen ^{[1
]}

Hu, Xin ^{[1
]}

Zeng, Yong-Fei ^{[1
]}

Bu, Xian-He ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

CRYSTENGCOMM | 2007年 / 9卷 / 10期

关键词：

D O I：

10.1039/b707622c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Ln(III) salts with 1,5-naphthalenedisulfonate (1,5-NDS) or 2,7-naphthalenedisulfonate ( 2,7-NDS), and phenanthroline ( phen) under hydrothermal conditions gave a series of new 2-D complexes {[Ln(1,5-NDS)(1.5)(phen)(2)(H2O)(2)]center dot 3H(2)O}(n) [Ln = Eu-III (1), Gd-III (2), Nd-III (3), Tb-III (4)] and dinuclear compounds [Ln(2)(2,7-NDS)(2)(mu(2)-OH)(2)(phen)(4)(H2O)(2)]center dot 4H(2)O [Ln = Eu-III ( 5), Gd-III (6), Tb-III (7)], respectively. 1-4 are puckered (6,3) networks with 1,5-NDS as a bridge and phen chelating to Ln(III) ions. 5-7 are hydroxyl bridged dinuclear entities, which extend to 2-D networks by H-bonds.

引用

页码：902 / 906

页数：5

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