Crystal Structure of Hydrazinium Iodide by Neutron Diffraction

被引：0

作者：

Campbell, Eric V. ^{[1
]}

Wang, Xiaoping ^{[2
]}

Miller, Joel S. ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, 315 S 1400 E, Salt Lake City, UT 84112 USA

[2] Oak Ridge Natl Lab, Neutron Scattering Div, Bethel Valley Rd, Oak Ridge, TN 37831 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2017年 / 47卷 / 06期

关键词：

Crystal structure; Hydrazine; Hydrazinium; Neutron diffraction; Hydrogen bonding; HYDROGEN-BOND; PHOSPHATE; SULFATE;

D O I：

10.1007/s10870-017-0704-0

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of hydrazinium iodide, [H5N2](+)center dot I-, at 100 K has monoclinic (P2(1)/n) symmetry from single crystal neutron diffraction with a = 7.4599(7) angstrom, b = 5.3185(6) angstrom, c = 10.1628(11) angstrom, beta = 103.150(10)degrees, V = 392.64(7) angstrom(3), Z = 4. The refinement converged to R = 0.0575, wR(2) = 0.1602, S = 1.022. Data for the crystal structure was collected on the SNS TOPAZ single-crystal time-of-flight Laue diffractometer. The compound has a one-dimensional structure which displays N-H center dot center dot center dot N hydrogen bonding. Accurate intra- and intermolecular N-H distances have been determined.

引用

页码：241 / 244

页数：4

共 28 条

[1]

Andrew M. R., 1972, Journal of Applied Electrochemistry, V2, P327, DOI 10.1007/BF00615280

[2]

BENNING CJ, 1969, PLASTIC FOAMS, V1

[3] Facile synthesis of ZnO nanorods by microwave irradiation of zinc-hydrazine hydrate complex [J].

Bhat, Denthaje Krishna .

NANOSCALE RESEARCH LETTERS, 2008, 3 (01) :31-35

[4] THE CRYSTAL STRUCTURE OF HYDRAZINE [J].

COLLIN, RL ;

LIPSCOMB, WN .

ACTA CRYSTALLOGRAPHICA, 1951, 4 (01) :10-14

[5]

Collis DE, 1974, KENT TECH REV, V12, P19

[6] Some thermodynamic functions and kinetics of thermal decomposition of NH4MnPO4 •A H2O in nitrogen atmosphere [J].

Danvirutai, Chanaiporn ;

Noisong, Pittayagorn ;

Youngme, Sujittra .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 100 (01) :117-124

[7] WinGX and ORTEP for Windows: an update [J].

Farrugia, Louis J. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :849-854

[8] THE IODIDES OF HYDRAZINE [J].

GILBERT, EC ;

DECIUS, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (15) :3871-3872

[9] High-resolution neutron crystallographic studies of the hydration of the coenzyme cob(II)alamin [J].

Jogl, Gerwald ;

Wang, Xiaoping ;

Mason, Sax A. ;

Kovalevsky, Andrey ;

Mustyakimov, Marat ;

Fisher, Zoee ;

Hoffman, Christina ;

Kratky, Christoph ;

Langan, Paul .

ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY, 2011, 67 :584-591

[10] NEUTRON AND X-RAY DIFFRACTION STUDIES OF HYDRAZINIUM SULFATE, N2H6SO4 [J].

JONSSON, PG ;

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 :536-&

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