Invited Review Article: Instrumentation for nuclear magnetic resonance in zero and ultralow magnetic field

被引:94
作者
Tayler, Michael C. D. [1 ,2 ]
Theis, Thomas [3 ]
Sjolander, Tobias F. [4 ]
Blanchard, John W. [5 ]
Kentner, Arne [6 ]
Pustelny, Szymon [7 ]
Pines, Alexander [4 ]
Budker, Dmitry [1 ,8 ,9 ]
机构
[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
[2] Univ Cambridge, Dept Chem Engn & Biotechnol, Cambridge, England
[3] Duke Univ, Dept Chem, Durham, NC 27708 USA
[4] Univ Calif Berkeley, Coll Chem, Berkeley, CA 94720 USA
[5] Helmholtz Inst Mainz, D-55099 Mainz, Germany
[6] Rhein Westfal TH Aachen, Aachen, Germany
[7] Jagiellonian Univ, Inst Phys, PL-30348 Krakow, Poland
[8] Lawrence Berkeley Natl Lab, Nucl Sci Div, Berkeley, CA 94720 USA
[9] Johannes Gutenberg Univ Mainz, Helmholtz Inst Mainz, Mainz, Germany
基金
美国国家科学基金会;
关键词
J-COUPLING SPECTROSCOPY; SPIN-EXCHANGE; NMR-SPECTROSCOPY; PARA-HYDROGEN; SENSITIVITY; MRI; PARAHYDROGEN; RELAXATION; MAGNETOMETRY; SIGNALS;
D O I
10.1063/1.5003347
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
We review experimental techniques in our laboratory for nuclear magnetic resonance (NMR) in zero and ultralow magnetic field (below 0.1 mu T) where detection is based on a low-cost, non-cryogenic, spin-exchange relaxation free Rb-87 atomic magnetometer. The typical sensitivity is 20-30 fT/Hz(1/2) for signal frequencies below 1 kHz and NMR linewidths range from Hz all the way down to tens of mHz. These features enable precision measurements of chemically informative nuclear spin-spin couplings as well as nuclear spin precession in ultralow magnetic fields. Published by AIP Publishing.
引用
收藏
页数:17
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