Fluorescent liquid pyrene derivative-in-water microemulsions

被引：32

作者：

Hollamby, M. J. ^{[1
]}

Danks, A. E. ^{[2
]}

Schnepp, Z. ^{[2
]}

Rogers, S. E. ^{[3
]}

Hart, S. R. ^{[4
]}

Nakanishi, T. ^{[5
]}

机构：

[1] Keele Univ, Sch Phys & Geog Sci, Keele ST5 5BG, Staffs, England

[2] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

[3] Rutherford Appleton Lab, ISIS STFC, Chilton OX11 0QX, Oxon, England

[4] Keele Univ, Inst Sci & Technol Med, Keele ST5 5BG, Staffs, England

[5] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 46期

关键词：

LIGHT-EMITTING DIODE; ANGLE NEUTRON-SCATTERING; ORGANIC SEMICONDUCTORS; NONIONIC SURFACTANTS; AQUEOUS-SOLUTIONS; MICELLAR GROWTH; C12E6; MICELLES; SIZE; DROPLETS; SHAPE;

D O I：

10.1039/c6cc01517d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fluorescent liquid pyrene derivative with a high fluorescence quantum yield (65%) in the bulk state is reported. With this as the sole oil phase, stable luminescent oil-in-water microemulsions have been prepared. Increasing the loading of liquid pyrene swells the droplets, as detected by small-angle neutron scattering. These larger droplets have a greater proportion of pyrene excimer emission contribution in their photoluminescence spectra, which leads to a red shift in the chromaticity of the emission.

引用

页码：7344 / 7347

页数：4

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