Room-temperature synthesis of aragonite crystals at an expanding liquid-liquid interface in a radial Hele-Shaw cell

被引：34
作者：
Rautaray, D
Banpurkar, A
Sainkar, SR
Limaye, AV
Pavaskar, NR
Ogale, SB
Sastry, M [1 ]
机构：
[1] Natl Chem Lab, Mat Chem Div, Pune 411008, Maharashtra, India
[2] Univ Poona, Dept Phys, Ctr Adv Studies Mat Sci, Pune 411007, Maharashtra, India
[3] Univ Maryland, Dept Phys, College Pk, MD 20742 USA
来源：
ADVANCED MATERIALS | 2003年 / 15卷 / 15期
关键词：
D O I：
10.1002/adma.200304535
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Large quantities of extremely fine aragonite needles (see Figure, top image) have been synthesized at room temperature at an expanding liquid-liquid interface in a radial Hele-Shaw cell. By simple variation of the experimental conditions, hollow, cylindrical aragonite/calcite crystals (see Figure, bottom image) may also be obtained. It is believed that this method can be extended to other materials and nanostructures.
引用
收藏
页码：1273 / +
页数：7
相关论文
共 48 条
[1]   Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver [J].
Aizenberg, J ;
Black, AJ ;
Whitesides, GH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4500-4509
[2]   SYNTHESIS OF NANOSIZE SILICA IN AEROSOL OT REVERSE MICROEMULSIONS [J].
ARRIAGADA, FJ ;
OSSEOASARE, K .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 170 (01) :8-17
[3]   THE FORMATION OF PATTERNS IN NONEQUILIBRIUM GROWTH [J].
BENJACOB, E ;
GARIK, P .
NATURE, 1990, 343 (6258) :523-530
[4]  
BONN D, 1995, PHYS REV LETT, V75, P2132, DOI 10.1103/PhysRevLett.75.2132
[5]   INTERACTIONS AT THE ORGANIC-INORGANIC INTERFACE - MOLECULAR DESIGN OF CRYSTALLIZATION INHIBITORS FOR BARITE [J].
BROMLEY, LA ;
COTTIER, D ;
DAVEY, RJ ;
DOBBS, B ;
SMITH, S ;
HEYWOOD, BR .
LANGMUIR, 1993, 9 (12) :3594-3599
[6]   Oriented crystallization of calcium carbonate under self-organized monolayers of amide-containing phospholipids [J].
Buijnsters, PJJA ;
Donners, JJJM ;
Hill, SJ ;
Heywood, BR ;
Nolte, RJM ;
Zwanenburg, B ;
Sommerdijk, NAJM .
LANGMUIR, 2001, 17 (12) :3623-3628
[7]   Growth of calcium carbonate crystals within fatty acid bilayer stacks [J].
Damle, C ;
Kumar, A ;
Sainkar, SR ;
Bhagawat, M ;
Sastry, M .
LANGMUIR, 2002, 18 (16) :6075-6080
[8]   A shape-persistent polymeric crystallization template for CaCO3 [J].
Donners, JJJM ;
Nolte, RJM ;
Sommerdijk, NAJM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) :9700-9701
[9]   Control of aragonite or calcite polymorphism by mollusk shell macromolecules [J].
Falini, G ;
Albeck, S ;
Weiner, S ;
Addadi, L .
SCIENCE, 1996, 271 (5245) :67-69
[10]   CALCITE CRYSTALLIZATION ON GELATIN FILMS CONTAINING POLYELECTROLYTES [J].
FALINI, G ;
GAZZANO, M ;
RIPAMONTI, A .
ADVANCED MATERIALS, 1994, 6 (01) :46-48
12345