Cost-Effective Synthesis of Amine-Tethered Porous Materials for Carbon Capture

被引：42

作者：

Lu, Weigang ^{[1
]}

Bosch, Mathieu ^{[1
]}

Yuan, Daqiang ^{[2
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHEMSUSCHEM | 2015年 / 8卷 / 03期

关键词：

carbon capture; energy efficiency; microporous materials; networks; polymers; TEMPERATURE SWING ADSORPTION; METAL-ORGANIC FRAMEWORK; CO2; CAPTURE; DIOXIDE CAPTURE; FLUE-GAS; POLYMER NETWORKS; SOLID SORBENTS; AQUEOUS MONOETHANOLAMINE; ADSORBENTS; CAPACITY;

D O I：

10.1002/cssc.201402622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A truly cost-effective strategy for the synthesis of amine-tethered porous polymer networks (PPNs) has been developed. A network containing diethylenetriamine (PPN-125-DETA) exhibits a high working capacity comparable to current state-of-art technology (30% monoethanolamine solutions), yet it requires only one third as much energy for regeneration. It has also been demonstrated to retain over 90% capacity after 50 adsorption-desorption cycles of CO2 in a temperature-swing adsorption process. The results suggest that PPN-125-DETA is a very promising new material for carbon capture from flue gas streams.

引用

页码：433 / 438

页数：6

共 56 条

[1]

[Anonymous], 2011, ANGEW CHEM, V123, P10360

[2]

[Anonymous], 2014, CLIMATE CHANGE

[3]

[Anonymous], 2010, ANGEW CHEM, V122, P6194

[4]

[Anonymous], 2014, ATM CO2 CONC

[5]

[Anonymous], 2012, ANGEW CHEM, V124, P7598

[6] Oxidative Stability of Amino Polymer-Alumina Hybrid Adsorbents for Carbon Dioxide Capture [J].

Bali, Sumit ;

Chen, Thomas T. ;

Chaikittisilp, Watcharop ;

Jones, Christopher W. .

ENERGY & FUELS, 2013, 27 (03) :1547-1554

[7] Adsorption of CO2-Containing Gas Mixtures over Amine-Bearing Pore-Expanded MCM-41 Silica: Application for Gas Purification [J].

Belmabkhout, Youssef ;

Serna-Guerrero, Rodrigo ;

Sayari, Abdelhamid .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (01) :359-365

[8] Comparing Physisorption and Chemisorption Solid Sorbents for use Separating CO2 from Flue Gas using Temperature Swing Adsorption [J].

Berger, Adam Hughmanick ;

Bhown, Abhoyjit S. .

10TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, 2011, 4 :562-567

[9] Carbon capture and storage update [J].

Boot-Handford, M. E. ;

Abanades, J. C. ;

Anthony, E. J. ;

Blunt, M. J. ;

Brandani, S. ;

Mac Dowell, N. ;

Fernandez, J. R. ;

Ferrari, M. -C. ;

Gross, R. ;

Hallett, J. P. ;

Haszeldine, R. S. ;

Heptonstall, P. ;

Lyngfelt, A. ;

Makuch, Z. ;

Mangano, E. ;

Porter, R. T. J. ;

Pourkashanian, M. ;

Rochelle, G. T. ;

Shah, N. ;

Yao, J. G. ;

Fennell, P. S. .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (01) :130-189

[10] Poly(allylamine)-Mesoporous Silica Composite Materials for CO2 Capture from Simulated Flue Gas or Ambient Air [J].

Chaikittisilp, Watcharop ;

Khunsupat, Ratayakorn ;

Chen, Thomas T. ;

Jones, Christopher W. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (24) :14203-14210

← 1 2 3 4 5 6 →