Synthesis of Novel Fluorine-Containing 1,3-Dithiolium Derivatives

被引：0

作者：

Bahrin, Lucian Gabriel ^{[1
]}

Hopf, Henning ^{[2
]}

Jones, Peter George ^{[3
]}

Poroch, Vladimir ^{[4
]}

Birsa, Lucian Mihail ^{[1
]}

机构：

[1] Alexandru Ioan Cuza Univ, Dept Chem, 11 Carol Blvd, Iasi 700506, Romania

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, Hagenring 30, D-38106 Braunschweig, Germany

[3] Tech Univ Carolo Wilhelmina Braunschweig, Inst Inorgan & Analyt Chem, Hagenring 30, D-38106 Braunschweig, Germany

[4] Grigore T Popa Univ Med & Pharm Iasi, Dept Surg, 16 Univ St, Iasi 700115, Romania

来源：

REVISTA DE CHIMIE | 2016年 / 67卷 / 03期

关键词：

fluorine derivatives; dithiocarbamate; 1,3-dithiolium salt; mesoionic phenolate; X-ray crystallography; medicinal chemistry; drug design; MEDICINAL CHEMISTRY; PHARMACEUTICALS; SALTS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of 4-(5-fluoro-2-hydroxyphenyl)-2-N,N-diethylamino-1,3-dithiol-2-ylium perchlorate has been accomplished by the acid-catalyzed cyclization of 1-(5-fluoro-2-hydroxyphenyl)-1-oxaethan-2-yl-N,N-chethylamino-1-carbodithioate. The structure of the new phenacyl carbodithioate was confirmed by X-ray analysis. Conversion of the 1,3-dithiolium perchlorate into a mesoionic derivative was achieved in a basic environment

引用

页码：481 / 484

页数：4

共 37 条

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