Observation of a uniaxial ferroelectric smectic A phase

被引:44
作者
Chen, Xi [1 ,2 ]
Martinez, Vikina [1 ,2 ]
Nacke, Pierre [3 ]
Korblova, Eva [4 ]
Manabe, Atsutaka [5 ]
Klasen-Memmer, Melanie [5 ]
Freychet, Guillaume [6 ]
Zhernenkov, Mikhail [6 ]
Glaser, Matthew A. [1 ,2 ]
Radzihovsky, Leo [1 ,2 ]
Maclennan, Joseph E. [1 ,2 ]
Walba, David M. [4 ]
Bremer, Matthias [5 ]
Giesselmann, Frank [3 ]
Clark, Noel A. [1 ,2 ]
机构
[1] Univ Colorado Boulder, Dept Phys, Boulder, CO 80309 USA
[2] Univ Colorado Boulder, Soft Mat Res Ctr, Boulder, CO 80309 USA
[3] Univ Stuttgart, Inst Phys Chem, D-70569 Stuttgart, Germany
[4] Univ Colorado Boulder, Dept Chem, Boulder, CO 80309 USA
[5] Merck KGaA, Elect Div, D-64293 Darmstadt, Germany
[6] Brookhaven Natl Lab, Natl Synchrotron Light Source II, Upton, NY 11973 USA
关键词
liquid crystal; ferroelectric; smectic; nematic; SPIN-GAS MODEL; LIQUID-CRYSTALS;
D O I
10.1073/pnas.2210062119
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We report the observation of the smectic AF, a liquid crystal phase of the ferroelectric nematic realm. The smectic AF is a phase of small polar, rod-shaped molecules that form two-dimensional fluid layers spaced by approximately the mean molecular length. The phase is uniaxial, with the molecular director, the local average long-axis orientation, normal to the layer planes, and ferroelectric, with a spontaneous electric polarization parallel to the director. Polarization measurements indicate almost complete polar ordering of the similar to 10 Debye longitudinal molecular dipoles, and hysteretic polarization reversal with a coercive field similar to 2 x 10(5) V/m is observed. The SmA(F) phase appears upon cooling in two binary mixtures of partially fluorinated mesogens: 2N/DIO, exhibiting a nematic (N)-smectic Z(A) (SmZ(A))-ferroelectric nematic (N-F)-SmA(F) phase sequence, and 7N/DIO, exhibiting an N-SmZ(A)-SmAF phase sequence. The latter presents an opportunity to study a transition between two smectic phases having orthogonal systems of layers.
引用
收藏
页数:10
相关论文
共 41 条
[1]   FRUSTRATED SPIN-GAS MODEL FOR DOUBLY REENTRANT LIQUID-CRYSTALS [J].
BERKER, AN ;
WALKER, JS .
PHYSICAL REVIEW LETTERS, 1981, 47 (20) :1469-1472
[2]  
BLINOV LM, 1993, J PHYS II, V3, P1121, DOI 10.1051/jp2:1993187
[3]  
Born M., 1916, Sitzungsber. K. Preuss. Akad. Wiss, V30, P614
[4]  
Chen X, 2022, INT LIQUID CRYSTAL C
[5]  
Chen X., FERROELECTRIC SMECTI
[6]  
Chen X, 2021, Arxiv, DOI [arXiv:2012.15335, 10.48550/arXiv.2012.15335, DOI 10.48550/ARXIV.2012.15335]
[7]  
Chen X, 2022, Arxiv, DOI [arXiv:2206.12965, 10.48550/arXiv.2206.12965, DOI 10.48550/ARXIV.2206.12965]
[8]  
Chen X, 2021, Arxiv, DOI [arXiv:2112.14222, 10.48550/arXiv.2112.14222, DOI 10.48550/ARXIV.2112.14222]
[9]   Ideal mixing of paraelectric and ferroelectric nematic phases in liquid crystals of distinct molecular species [J].
Chen, Xi ;
Zhu, Zhecong ;
Magrini, Mitchell J. ;
Korblova, Eva ;
Park, Cheol S. ;
Glaser, Matthew A. ;
Maclennan, Joseph E. ;
Walba, David M. ;
Clark, Noel A. .
LIQUID CRYSTALS, 2022, 49 (11) :1531-1544
[10]   Polar in-plane surface orientation of a ferroelectric nematic liquid crystal: Polar monodomains and twisted state electro-optics [J].
Chen, Xi ;
Korblova, Eva ;
Glaser, Matthew A. ;
Maclennan, Joseph E. ;
Walba, David M. ;
Clark, Noel A. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2021, 118 (22)