The effect of solubility on the stability of titanium(IV) arene complexes derived from hexasubstituted arenes and TiCl4

被引：11
作者：
Kiprof, P
Li, J
Renish, CL
Kalombo, EK
Young, VG
机构：
[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA
[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 620卷 / 1-2期
关键词：
arene complexes; high-valent; titanium; stability; solubility;
D O I：
10.1016/S0022-328X(00)00852-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The investigation of new titanium(IV) hexaalkylarene complexes gave new insight into the stability of high-valent metal arene complexes. In contrast to low-valent transition metal arene complexes these complexes are in equilibrium with the free arenes. The stability of the complexes was shown to depend strongly on both the donor ability of the arene and on their solubility. This is unprecedented in transition metal arene chemistry. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：113 / 118
页数：6
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