Addition to electron deficient olefins of α-oxy carbon-centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy-λ3-iodane

被引：12

作者：

Sueda, T ^{[1
]}

Takeuchi, Y ^{[1
]}

Suefuji, T ^{[1
]}

Ochiai, M ^{[1
]}

机构：

[1] Univ Tokushima, Fac Pharmaceut Sci, Tokushima 7708505, Japan

来源：

MOLECULES | 2005年 / 10卷 / 01期

关键词：

radical; iodane; ether; vinyl sulfone; maleate;

D O I：

10.3390/10010195

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.

引用

页码：195 / 200

页数：6