Corrosion performance of plasma electrolytic oxidized AZ31 magnesium alloy in silicate solutions with different additives

被引:67
作者
Chen, Huan [1 ]
Lv, GuoHua [1 ]
Zhang, GuLing [2 ]
Pang, Hua [1 ]
Wang, XingQuan [3 ]
Lee, HeonJu [4 ]
Yang, SiZe [1 ,5 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
[2] Cent Univ Nationalities, Coll Sci, Beijing 100081, Peoples R China
[3] Changchun Univ Sci & Technol, Coll Sci, Changchun 130022, Jilin, Peoples R China
[4] Cheju Natl Univ, Fac Mech & Energy Syst Engn, Cheju 690756, South Korea
[5] Xiamen Univ, Sch Phys & Mech & Elect Engn, Fujian Key Lab Plasma & Magnet Resonance, Xiamen 363105, Peoples R China
基金
中国国家自然科学基金;
关键词
Plasma electrolytic oxidation; AZ31 Magnesium alloy; Silicate; Phosphate; Fluoride; Corrosion resistance; MICRO-ARC OXIDATION; COATINGS; AZ91D; RESISTANCE; FLUORIDE; GROWTH;
D O I
10.1016/j.surfcoat.2010.03.032
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, plasma electrolytic oxidation coatings were produced on AZ31 magnesium alloy. The electrolytes used were mainly composed of silicate, silicate with addition of phosphate or fluoride, respectively. Scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis, X-ray diffraction (XRD), and potentiodynamic polarization tests were carried out to investigate the microstructure, element composition, phase composition and corrosion resistance of the coatings. The results showed that the coating formed in silicate electrolyte was mainly composed of MgO. Mg2SiO4 and had a dense structure and low thickness. After the addition of fluoride, MgF2 was formed and both the coating thickness and corrosion resistance were increased. The addition of phosphate also quickened the film growth rate, but the corrosion resistance of the coating was reduced instead due to the loose and porous microstructure. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:S32 / S35
页数:4
相关论文
共 15 条
[1]   The role of the magnesium industry in protecting the environment [J].
Aghion, E ;
Bronfin, B ;
Eliezer, D .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2001, 117 (03) :381-385
[2]   Electrochemical performance of microarc oxidation films formed on AZ91D magnesium alloy in silicate and phosphate electrolytes [J].
Cai, QZ ;
Wang, LS ;
Wei, BK ;
Liu, QX .
SURFACE & COATINGS TECHNOLOGY, 2006, 200 (12-13) :3727-3733
[3]   Growth process of plasma electrolytic oxidation films formed on magnesium alloy AZ91D in silicate solution [J].
Duan, Hongping ;
Yan, Chuanwei ;
Wang, Fuhui .
ELECTROCHIMICA ACTA, 2007, 52 (15) :5002-5009
[4]   Effect of electrolyte additives on performance of plasma electrolytic oxidation films formed on magnesium alloy AZ91D [J].
Duan, Hongping ;
Yan, Chuanwei ;
Wang, Fuhui .
ELECTROCHIMICA ACTA, 2007, 52 (11) :3785-3793
[5]   Study of the structure and corrosion behavior of PEO coatings on AM50 maginesium. alloy by electrochemical impedance spectroscopy [J].
Ghasemi, A. ;
Raja, V. S. ;
Blawert, C. ;
Dietzel, W. ;
Kainer, K. U. .
SURFACE & COATINGS TECHNOLOGY, 2008, 202 (15) :3513-3518
[6]   Formation of oxygen bubbles and its influence on current efficiency in micro-arc oxidation process of AZ91D magnesium alloy [J].
Guo, HF ;
An, MZ ;
Xu, S ;
Huo, HB .
THIN SOLID FILMS, 2005, 485 (1-2) :53-58
[7]   Growth of ceramic coatings on AZ91D magnesium alloys by micro-arc oxidation in aluminate-fluoride solutions and evaluation of corrosion resistance [J].
Guo, HF ;
An, MZ .
APPLIED SURFACE SCIENCE, 2005, 246 (1-3) :229-238
[8]   Corrosion rate of magnesium and its alloys in buffered chloride solutions [J].
Inoue, H ;
Sugahara, K ;
Yamamoto, A ;
Tsubakino, H .
CORROSION SCIENCE, 2002, 44 (03) :603-610
[9]   Anodizing of pure magnesium in KOH-aluminate solutions under sparking [J].
Khaselev, O ;
Weiss, D ;
Yahalom, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (05) :1757-1761
[10]   Effects of NaAlO2 on structure and corrosion resistance of microarc oxidation coatings formed on AM60B magnesium alloy in phosphate-KOH electrolyte [J].
Liang, J ;
Guo, BG ;
Tian, J ;
Liu, HW ;
Zhou, JF ;
Liu, WM ;
Xu, T .
SURFACE & COATINGS TECHNOLOGY, 2005, 199 (2-3) :121-126