Ionic Liquids and Deep Eutectic Solvents for CO2 Conversion Technologies-A Review

被引:29
作者
Maniam, Kranthi Kumar [1 ]
Paul, Shiladitya [1 ,2 ]
机构
[1] Univ Leicester, Mat Innovat Ctr, Sch Engn, Leicester LE1 7RH, Leics, England
[2] TWI, Mat & Struct & Integr Technol Grp, Cambridge CB21 6AL, England
基金
欧盟地平线“2020”;
关键词
renewable energy; electrochemical conversion; carbon dioxide reduction; functionalized ionic liquids (ILs); carbon dioxide transformation; CARBON-DIOXIDE; ELECTROCATALYTIC CARBOXYLATION; ELECTROCHEMICAL ACTIVATION; DIMETHYL CARBONATE; REDUCTION; ELECTRODE; ELECTROREDUCTION; TRANSFORMATION; TRANSITION; CHALLENGES;
D O I
10.3390/ma14164519
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ionic liquids (ILs) have a wide range of potential uses in renewable energy, including CO2 capture and electrochemical conversion. With the goal of providing a critical overview of the progression, new challenges, and prospects of ILs for evolving green renewable energy processes, this review emphasizes the significance of ILs as electrolytes and reaction media in two primary areas of interest: CO2 electroreduction and organic molecule electrosynthesis via CO2 transformation. Herein, we briefly summarize the most recent advances in the field, as well as approaches based on the electrochemical conversion of CO2 to industrially important compounds employing ILs as an electrolyte and/or reaction media. In addition, the review also discusses the advances made possible by deep eutectic solvents (DESs) in CO2 electroreduction to CO. Finally, the critical techno-commercial issues connected with employing ILs and DESs as an electrolyte or ILs as reaction media are reviewed, along with a future perspective on the path to rapid industrialization.
引用
收藏
页数:20
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