Thermally stable gold(I) ethylene adducts:: [(HB{3,5-(CF3)2Pz}3)-Au(CH2=CH2)] and [(HB{3-(CF3),5-(Ph)Pz}3)Au(CH2=CH2)]

被引：64

作者：

Dias, H. V. Rasika ^{[1
]}

Wu, Jiang ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

ethylene; gold; N ligands; structure elucidation;

D O I：

10.1002/anie.200703328

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Captured by scorpionates: Using fluorinated scorpionates, remarkably stable gold (I) complexes containing ethylene are isolated and structurally characterized (see structure of molecule core: yellow Au, blue N, red B, light gray C). These adducts feature κ2- bonded tris(pyrazolyl)borate ligands, and show in the 1H and 13C NMR spectra considerably upfield-shifted ethylene signals. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7814 / 7816

页数：3

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