Studies of glycolysis of poly(ethylene terephthalate) recycled from postconsumer soft-drink bottles. II. Factorial experimental design

被引:23
作者
Chen, CH
Chen, CY
Lo, YW
Mao, CF
Liao, WT
机构
[1] So Taiwan Univ Technol, Dept Chem Engn, Yung Kang City, Tainen Hsien, Taiwan
[2] ScinoPharm Taiwan Ltd, Tainan, Taiwan
关键词
factorial experimental design; recycled poly(ethylene terephthalate) flake; glycolysis temperature; glycolysis time; amount of catalyst; glycolysis conversion;
D O I
10.1002/app.1176.abs
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Glycolysis temperature, glycolysis time, and amount of catalyst are important factors affecting the glycolysis of recycled poly(ethylene terephthalate) (PET) flakes. A 2(3) factorial experimental design is applied to study the main, two-factor interaction, and three-factor interaction effects of glycolysis temperature, glycolysis time, and amount of catalyst on the glycolysis of recycled PET flakes. In this study cobalt acetate is used as the glycolysis catalyst. The sequence of the main effects on the glycolysis conversion of the recycled PET flakes in ascending order is glycolysis time < glycolysis temperature < amount of catalyst. The sequence of the two-factor interaction effects on the glycolysis conversion of the recycled PET flakes in ascending order is glycolysis temperature versus the glycolysis time ( glycolysis time versus the amount of catalyst ( glycolysis temperature versus the amount of catalyst. The three-factor interaction effect is significantly related to the glycolysis conversion of the recycled PET flakes. (C) 2001 John Wiley & Sons, Inc.
引用
收藏
页码:956 / 962
页数:7
相关论文
共 12 条
  • [1] DEGRADABLE POLYMERS
    ALBERTSSON, AC
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1993, A30 (9-10): : 757 - 765
  • [2] BAMBRICK CR, 1993, SOC PLASTICS ENG ANT, V2, P1797
  • [3] Chen CH, 1999, J APPL POLYM SCI, V73, P2755, DOI 10.1002/(SICI)1097-4628(19990923)73:13<2755::AID-APP24>3.0.CO
  • [4] 2-7
  • [5] CHEN CH, IN PRESS J APPL POLY
  • [6] EDGE M, 1993, J MOL SCI PURE APP A, V30, P768
  • [7] HAHN GJ, 1975, CHEMTECH, P561
  • [8] HAHN GJ, 1975, CHEMTECH, P496
  • [9] ENVIRONMENTAL AGING AND STRESS-CRACKING OF POLY(ETHYLENE-TEREPHTHALATE)
    JABARIN, SA
    LOFGREN, EA
    [J]. POLYMER ENGINEERING AND SCIENCE, 1992, 32 (02) : 146 - 156
  • [10] PRIMARY THERMAL-DEGRADATION MECHANISMS OF PET AND PBT
    MONTAUDO, G
    PUGLISI, C
    SAMPERI, F
    [J]. POLYMER DEGRADATION AND STABILITY, 1993, 42 (01) : 13 - 28