The 2:1 adduct of 8-hydroxyquinoline N-oxide and diaquabis(8-hydroxyquinoline N-oxide)dithiocyanatocobalt(II)

被引：4
|
作者：
Zhang, Shi-Guo
Xu, Hai-Yan
Shi, Jing-Min [1 ]
机构：
[1] Binzhou Univ, Inst Mat Chem, Dept Chem & Chem Engn, Binzhou 256603, Peoples R China
[2] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807032722
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the title adduct, [Co(NCS)(2)-(C9H7NO2)(2)(H2O)(2)]center dot 2C(9)H(7)NO(2), the uncoordinated 8-hydroxyquinoline molecules and complex molecules are connected by intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen bonds. In the complex molecule, the Coll atom lies on a crystallographic inversion centre and has a slightly distorted octahedral coordination geometry. In addition, weak pi-pi stacking interactions between the uncoordinated and coordinated ring systems, with ring-centroid separations of 3.7554 (18) angstrom, consolidate the crystal structure.
引用
收藏
页码：M2083 / U556
页数：11
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