Double-shell CeO2:Yb, Er@SiO2@Ag upconversion composite nanofibers as an assistant layer enhanced near-infrared harvesting for dye-sensitized solar cells

被引：15

作者：

Zhao, Rongfang ^{[1
,2
]}

Wu, Qianhui ^{[1
]}

Tang, Dongmei ^{[1
]}

Li, Wenlong ^{[1
]}

Zhang, Xiue ^{[1
]}

Chen, Ming ^{[1
]}

Guo, Rong ^{[1
]}

Diao, Guowang ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2018年 / 769卷

基金：

中国国家自然科学基金;

关键词：

CeO2:Yb; Er@SiO2@Ag; Upconversion luminescence; Near-infrared absorption; Assistant layer; Dye-sensitized solar cells; PERFORMANCE; EFFICIENCY; SEPARATION;

D O I：

10.1016/j.jallcom.2018.07.225

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Double-shell CeO2:Yb,Er@SiO2@ Ag upconversion composite nanofibers are synthesized by electro- spinning and subsequent process. CeO2:Yb,Er@SiO2@ Ag nanofibers show high upconversion luminescence property due to the coating of amorphous SiO2 and the surface plasmon resonance effect of Ag nanoparticles. CeO2:Yb,Er@SiO2@ Ag nanofibers act as an assistant layer in dye-sensitized solar cells (DSSCs) and enhance the photoelectric conversion efficiency (PCE) to 8.17%. The photocurrent-voltage characteristic is obtained under 980 nm laser as illumination light source. In addition, the absorption of the incident photon-to-current conversion efficiency curve in 900-1000 nm near-infrared light confirms that the introduction of the upconversion nanomaterial broadens the absorption range, improves the utilization rate of the sunlight and increases the PCE of DSSCs. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：92 / 95

页数：4

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