Ionic Liquids as Fragrance Precursors: Smart Delivery Systems for Volatile Compounds

被引:21
作者
Berton, Paula [1 ]
Shamshina, Julia L. [2 ]
Bica, Katharina [3 ]
Rogers, Robin D. [4 ]
机构
[1] Univ Calgary, Chem & Petr Engn Dept, Calgary, AB T2N 1N4, Canada
[2] Mari Signum Midatlantic LLC, 3204 Tower Oaks Blvd, Rockville, MD 20852 USA
[3] Vienna Univ Technol, Inst Appl Synthet Chem, Getreidemarkt 9-163, A-1060 Vienna, Austria
[4] 525 Solut Inc, POB 2206, Tuscaloosa, AL 35403 USA
关键词
CONTROLLED-RELEASE; ESSENTIAL OIL; SOLVENTS; ENCAPSULATION; DISTILLATION; EXTRACTION; EVOLUTION;
D O I
10.1021/acs.iecr.8b02903
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The low volatility of many ionic liquids (ILs) can be used to design a specific delivery system with a triggered release mechanism for volatile fragrances. We present two different strategies for IL-supported profragrance compounds based on common fragrance alcohols. When the fragrance was attached to the cation, its release was triggered by heat, while the fragrance attached to the anion was released under basic conditions. Selection of the counterion allowed not only control of the physical properties of the resulting compound but also addition of a second functionality. Our design strategy shows that the choice of the IL components can result in safe, biocompatible ionic profragrances suitable for applications such as topical nutraceutical or cosmetic formulations.
引用
收藏
页码:16069 / 16076
页数:8
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