Design and Synthesis of Photoactive Iron N-Heterocyclic Carbene Complexes

被引:43
|
作者
Kaufhold, Simon [1 ]
Waernmark, Kenneth [1 ]
机构
[1] Lund Univ, Ctr Anal & Synth, Box 124, S-22100 Lund, Sweden
基金
瑞典研究理事会;
关键词
iron; N-heterocyclic carbenes; NHCs; coordination chemistry; photophysics; photochemistry; EXCITED-STATE PROPERTIES; ELECTRONIC-STRUCTURE; FE(II) COMPLEXES; LIGAND; PHOTOSENSITIZERS; LIGHT; DYNAMICS; LIFETIME; SYSTEMS; TIO2;
D O I
10.3390/catal10010132
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of iron in photoactive metal complexes has been investigated for decades. In this respect, the charge transfer (CT) states are of particular interest, since they are usually responsible for the photofunctionality of such compounds. However, only recently breakthroughs have been made in extending CT excited state lifetimes that are notoriously short-lived in classical polypyridine iron coordination compounds. This success is in large parts owed to the use of strongly sigma-donating N-heterocyclic carbene (NHC) ligands that help manipulating the photophysical and photochemical properties of iron complexes. In this review we aim to map out the basic design principles for the generation of photofunctional iron NHC complexes, summarize the progress made so far and recapitulate on the synthetic methods used. Further, we want to highlight the challenges still existing and give inspiration for future generations of photoactive iron complexes.
引用
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页数:31
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