Donor-acceptor-donor type conjugated polymers for electrochromic applications: benzimidazole as the acceptor unit

被引：64

作者：

Akpinar, Hava ^{[1
]}

Balan, Abidin ^{[1
]}

Baran, Derya ^{[1
]}

Unver, Elif Kose ^{[1
]}

Toppare, Levent ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, Dept Biotechnol, Dept Polymer Sci & Technol, TR-06531 Ankara, Turkey

来源：

POLYMER | 2010年 / 51卷 / 26期

关键词：

Benzimidazole; Donor-acceptor approach; Electrochromism; BAND-GAP; ELECTROCHEMICAL PROPERTIES; NEUTRAL STATE; CONDUCTIVITY;

D O I：

10.1016/j.polymer.2010.10.045

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Donor-acceptor-donor (DAD) type benzimidazole (Blm) and 3,4 ethylenedioxythiophene (EDOT) bearing monomers were synthesized and electrochemically polymerized. Pendant group at 2-C position of the imidazole ring was functionalized with phenyl (P1), EDOT (P2) and ferrocene (P3) in order to observe substituent effect on electrochemical and electrochromic properties of corresponding polymers. Spectroelectrochemical results showed that different pendant groups resulted in polymers with slightly different optical band gaps (1.75, 1.69 and 1.77 eV respectively) and different number of achievable colored states. Optoelectronic performance and comparison of results with other well known pi-accepting benzazole bearing DAD type polymers were reported in detail. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：6123 / 6131

页数：9

共 50 条

[31] Chalcogenodiazolo[3,4-c]pyridine based donor-acceptor-donor polymers for green and nearinfrared electrochromics [J].

Ming, Shouli ;

Zhen, Shijie ;

Liu, Ximei ;

Lin, Kaiwen ;

Liu, Hongtao ;

Zhao, Yao ;

Lu, Baoyang ;

Xu, Jingkun .

POLYMER CHEMISTRY, 2015, 6 (48) :8248-8258

[32] Design principles for the energy level tuning in donor/acceptor conjugated polymers [J].

Hashemi, Daniel ;

Ma, Xiao ;

Ansari, Ramin ;

Kim, Jinsang ;

Kieffer, John .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (02) :789-799

[33] Spectral Engineering in π-Conjugated Polymers with Intramolecular Donor-Acceptor Interactions [J].

Beaujuge, Pierre M. ;

Amb, Chad M. ;

Reynolds, John R. .

ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (11) :1396-1407

[34] Electrosynthesis and Characterization of the Donor-Acceptor Type Multicolored Electrochromic Materials [J].

Hou Yingfei ;

Xu Gangqiang ;

Zhao Jinsheng ;

Kong Ying ;

Yang Chong .

ACTA CHIMICA SINICA, 2014, 72 (12) :1238-1244

[35] Pyrrolophthalazine dione (PPD)-based donor-acceptor polymers as high performance electrochromic materials [J].

Ye, Qun ;

Neo, Wei Teng ;

Lin, Tingting ;

Song, Jing ;

Yan, Hong ;

Zhou, Hui ;

Shah, Kwok Wei ;

Chua, Soo Jin ;

Xu, Jianwei .

POLYMER CHEMISTRY, 2015, 6 (09) :1487-1494

[36] Electrochromic conjugated porous polymers based on N,N,N′, N′-tetraphenyl-1,4-phenylenediamine with donor-donor and donor-acceptor structures [J].

Bo, Xiangfeng ;

Zhong, Xiujuan ;

Ming, Shouli ;

Zhang, Yan ;

Zhao, Jinsheng .

EUROPEAN POLYMER JOURNAL, 2025, 230

[37] Electrochemical preparation of donor-acceptor type conjugated polymer films: Effect of substitute units on electrochromic performance [J].

Akgul, Eda Taga ;

Uzdurmez, Ahmet Ferat ;

Kamis, Handan ;

Kilic, Emine ;

Demir, Muslum .

OPTICAL MATERIALS, 2021, 111

[38] Donor acceptor type neutral state green polymer bearing pyrrole as the donor unit [J].

Celebi, Selin ;

Balan, Abidin ;

Epik, Bugra ;

Baran, Derya ;

Toppare, Levent .

ORGANIC ELECTRONICS, 2009, 10 (04) :631-636

[39] Optoelectronic Applications of Conjugated Organic Polymers: Influence of Donor/Acceptor Groups through Density Functional Studies [J].

Garg, Shivangi ;

Goel, Neetu .

JOURNAL OF PHYSICAL CHEMISTRY C, 2022, 126 (22) :9313-9323

[40] Linker effects on optoelectronic properties of alternate donor-acceptor conjugated polymers [J].

Li, Jing ;

Yan, Ming ;

Xie, Yu ;

Qiao, Qiquan .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :4276-4283

← 1 2 3 4 5 →