Molecule-Electrode Bonding Design for High Single-Molecule Conductance

被引：24

作者：

Yokota, Kazumichi ^{[1
]}

Taniguchi, Masateru ^{[1
,2
]}

Tsutsui, Makusu ^{[1
]}

Kawai, Tomoji ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 49期

基金：

日本学术振兴会;

关键词：

COUPLING EFFICIENCY; TRANSPORT; SULFUR;

D O I：

10.1021/ja108032q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the application of an intermolecular interaction design for organic conductor crystals with a high conductance to a molecule-electrode design for a high single-molecule conductance by using dithiol and diselenol terthiophenes. We found that dithiol and diselenol single-molecule junctions show the highest single-molecule conductance among single-molecule junctions with Au-S and Au-Se bonds, and that diselenol single-molecule junctions have a higher single-molecule conductance than dithiol ones. We demonstrate that replacing S atoms with Se atoms is a promising molecule-electrode bonding design for a high single-molecule conductance.

引用

页码：17364 / 17365

页数：2

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