Excess molar enthalpies of (acetonitrile plus butan-2-one) and (methanol plus acetonitrile plus butan-2-one) at T = 298.15

被引：2

作者：

Tamura, K ^{[1
]}

Watanabe, M ^{[1
]}

Tsuchiya, S ^{[1
]}

Yamada, T ^{[1
]}

机构：

[1] Kanazawa Univ, Div Phys Sci, Dept Chem & Chem Engn, Kanazawa, Ishikawa 9208667, Japan

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2001年 / 33卷 / 01期

关键词：

excess enthalpy; ternary mixture; association; model;

D O I：

10.1006/jcht.2000.0721

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The excess molar enthalpies of (acetonitrile + butan-2-one) and (methanol + acetonitrile + butan-2-one) were measured at T = 298.15 K and atmospheric pressure using a flow microcalorimeter. The experimental results are correlated with polynomial equations and compared with those calculated from associated solution models taking account into self-association of methanol and acetonitrile as well as solvation between unlike molecules and a non-polar interaction term. (C) 2001 Academic Press.

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页码：95 / 102

页数：8

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