Thiophene-containing Schiff-base macrocycles: intermediate compounds between macroaromatics and azamacrocycles

被引：18
作者：
Won, DH
Lee, CH [1 ]
机构：
[1] Kangweon Natl Univ, Inst Basic Sci, Chunchon 200701, South Korea
[2] Kangweon Natl Univ, Dept Chem, Chunchon 200701, South Korea
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期
关键词：
Schiff-base; expanded porphyrins; penta-azamacrocycles; chiral receptors;
D O I：
10.1016/S0040-4039(01)00093-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hybrid Schiff-base macrocycles were synthesized by acid-catalysed condensation of 1,14-bisformyl-16-thiatripyrromethane 1 with diamines. The condensation of aliphatic diamines with 1 resulted in the partially oxidized macrocycles 5-11. On the other hand, the condensation of aromatic diamines with 1 gave simply cyclized Schiff-base 16. Fully conjugated macrocycles were never formed and attempted oxidation of either macrocycles with various oxidants resulted in the extensive decomposition of the starting material. Hydride reduction of imine functions gave the new hybrid macrocycles. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：1969 / 1972
页数：4
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