Effect of Processing Routes on the Microstructure and Thermoelectric Properties of Half-Heusler TiFe0.5Ni0.5Sb1-xSnx (x=0, 0.05, 0.1, 0.2) Alloys

被引：9

作者：

Karati, Anirudha ^{[1
]}

Ghosh, Sanyukta ^{[2
]}

Mallik, Ramesh Chandra ^{[2
]}

Shabadi, Rajashekhara ^{[3
]}

Murty, B. S. ^{[1
,4
,5
]}

Varadaraju, U. V. ^{[1
]}

机构：

[1] Indian Inst Technol Madras, Dept Chem, Chennai, Tamil Nadu, India

[2] Indian Inst Sci, Dept Phys, Thermoelect Mat & Devices Lab, Bangalore, Karnataka, India

[3] Univ Lille, Fac Sci & Technol, UMET, Villeneuve Dascq, France

[4] Indian Inst Technol Madras, Dept Met & Mat Engn, Chennai, Tamil Nadu, India

[5] Indian Inst Technol Hyderabad, Kandi, India

来源：

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE | 2022年 / 31卷 / 01期

关键词：

intermetallic alloys; powder metallurgy; semiconductors; sintering; PERFORMANCE; PHASES; METAL;

D O I：

10.1007/s11665-021-06207-z

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Sn-doped TiFe0.5Ni0.5Sb1-xSnx (x = 0, 0.05, 0.1, 0.2) were synthesized by vacuum arc melting (VAM). In addition to the half-Heusler phase, secondary phases of Fe-Sb-rich compound and Ti-rich compounds were obtained after VAM. The alloys were then subjected to ball milling for 1 h and 5 h. Ball milling for 1h led to microcrystalline grains, while that for 5 h led to nanocrystalline grains. Ball milling followed by spark plasma sintering (SPS) at 1173 K led to significant reduction in size of secondary phases in the microstructure. The undoped sample exhibited a ZT of 0.008 at 873 K for both 1h and 5h BM-SPS samples.

引用

页码：305 / 317

页数：13

共 11 条

[1] Effect of Processing Routes on the Microstructure and Thermoelectric Properties of Half-Heusler TiFe0.5Ni0.5Sb1−xSnx (x = 0, 0.05, 0.1, 0.2) Alloys
Anirudha Karati
Sanyukta Ghosh
Ramesh Chandra Mallik
Rajashekhara Shabadi
B. S. Murty
U. V. Varadaraju
Journal of Materials Engineering and Performance, 2022, 31 : 305 - 317
[2] Thermoelectric and Magnetic Properties of Biphasic ZrFe0.5Ni0.5Sb Double Half-Heusler and ZrNiSb Half-Heusler Induced by Co Doping
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[4] Microstructure and Thermoelectric Properties of Mechanically Alloyed Zr0.5Hf0.5Ni0.8Pd0.2Sn0.99Sb0.01/WO3 Half-Heusler Composites
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[5] Synthesis and thermoelectric properties of Ti-substituted (Hf0.5Zr0.5)1-xTixNiSn0.998Sb0.002 Half-Heusler compounds
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[8] Thermoelectric properties of half-Heusler high-entropy Ti2NiCoSn1-xSb1+x (x=0.5, 1) alloys with VEC> 18
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SCRIPTA MATERIALIA, 2020, 186 : 375 - 380
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[10] Effects of Ir Substitution and Processing Conditions on Thermoelectric Performance of p-Type Zr0.5Hf0.5Co1-xIrxSb0.99Sn0.01 Half-Heusler Alloys
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