Practical approach for catalytic asymmetric allylation of aldehydes with a chiral bidentate titanium(IV) complex

被引：52

作者：

Kii, S

Maruoka, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

[2] Hokkaido Univ, Grad Sch Sci, Dept Chem, Sapporo, Hokkaido 0600810L, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期

关键词：

allylation; binaphthol; asymmetric reactions; titanium and compounds;

D O I：

10.1016/S0040-4039(01)00025-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new, chiral bidentate Ti(IV) complex of type 1 was successfully designed and can be utilized for simultaneous coordination to aldehyde carbonyls, thereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with allyltributyltin. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1935 / 1939

页数：5

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