Synthesis and molecular structure of a novel monocarbon hydridorhodacarborane: closo-2,7-(PPh(3))(2)-2-H-2-Cl-1-(NMe(3))-2,1-RhCB10H9

被引：15
作者：
Chizhevsky, IT [1 ]
Pisareva, IV [1 ]
Petrovskii, PV [1 ]
Bregadze, VI [1 ]
Dolgushin, FM [1 ]
Yanovsky, AI [1 ]
Struchkov, YT [1 ]
Hawthorne, MF [1 ]
机构：
[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90095
来源：
INORGANIC CHEMISTRY | 1996年 / 35卷 / 05期
关键词：
D O I：
10.1021/ic9509950
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Syntheses of novel 18- and 16-electron monocarbon closo-rhodacarboranes derived from nido-B10H12-CNMe(3) are reported. closo-2,7-(PPh(3))(2)-2-H-2Cl-1-(NMe(3))-2,1-RhCB10H9 (3) and closo-2-(PPh(3))-2-Cl-1-(NMe(3))-2,1-RhCB10H10 (4) were prepared by heating Rh(PPh(3))(3)Cl with nido-B(10)H(12)CNMe(3) in methanol. The molecular structure of 3 was determined by X-ray diffraction and represents the first structurally characterized hydride complex within the family of mononuclear icosahedral monocarbon metallacarboranes.
引用
收藏
页码：1386 / &
页数：4
相关论文
共 26 条
  • [1] METALLACARBORANES DERIVED FROM THE [C2B10H12]2- ANION - THE PREPARATION, MOLECULAR-STRUCTURE, AND PROPERTIES OF [4-(DPPE)-4-PD-1,6-C2B10H12], [4,4,4-H(PPH3)2-2-OME-4-IR-1,6-C2B10H11], AND [3-(DPPE)-3-PT-1,2-C2B9H11]
    ALCOCK, NW
    TAYLOR, JG
    WALLBRIDGE, MGH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (08): : 1805 - 1811
  • [2] METALLACARBORANES IN CATALYSIS .2. SYNTHESIS AND REACTIVITY OF CLOSO ICOSAHEDRAL BIS(PHOSPHINE)HYDRIDORHODACARBORANES AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2 UNUSUAL CLOSO-PHOSPHINERHODACARBORANE COMPLEXES
    BAKER, RT
    DELANEY, MS
    KING, RE
    KNOBLER, CB
    LONG, JA
    MARDER, TB
    PAXSON, TE
    TELLER, RG
    HAWTHORNE, MF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) : 2965 - 2978
  • [3] METALLACARBORANES IN CATALYSIS .8. .1. CATALYTIC HYDROGENOLYSIS OF ALKENYL ACETATES .2. CATALYTIC ALKENE ISOMERIZATION AND HYDROGENATION REVISITED
    BELMONT, JA
    SOTO, J
    KING, RE
    DONALDSON, AJ
    HEWES, JD
    HAWTHORNE, MF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7475 - 7486
  • [4] THE CROWN ETHER PROMOTED BASE DEGRADATION OF P-CARBORANE
    BUSBY, DC
    HAWTHORNE, MF
    [J]. INORGANIC CHEMISTRY, 1982, 21 (11) : 4101 - 4103
  • [5] FACILE CONVERSION OF THE DIMERIC [(PH3PRHB10H10CNH2)2H]-[PPN]+ CLUSTER TO 16-ELECTRON MONONUCLEAR CLOSO-RHODACARBORANES BY N-QUATERNIZATION
    CHIZHEVSKY, IT
    PISAREVA, IV
    PETROVSKII, PV
    BREGADZE, VI
    YANOVSKY, AI
    STRUCHKOV, YT
    KNOBLER, CB
    HAWTHORNE, MF
    [J]. INORGANIC CHEMISTRY, 1993, 32 (16) : 3393 - 3394
  • [6] CHIZHEVSKY IT, 1991, METALLOORG KHIM, V4, P1416
  • [7] A DESIGNED METALLACARBORANE CATALYST - SYNTHESIS, STRUCTURE, AND REACTIONS OF [CLOSO-1,3-[MU-(ETA-2-3-CH2=CHCH2CH2)]-3-H-3-PPH3-3,1,2-RHC2B9H10]
    DELANEY, MS
    KNOBLER, CB
    HAWTHORNE, MF
    [J]. INORGANIC CHEMISTRY, 1981, 20 (05) : 1341 - 1347
  • [8] DOI JA, 1984, INORG CHEM, V23, P1482, DOI 10.1021/ic00178a035
  • [9] SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF 1,1-(PPH3)2-1-H-1,2,4-RHC2B10H12, A SUPRA-ICOSAHEDRAL METALLACARBABORANE CATALYST PRECURSOR
    HEWES, JD
    KNOBLER, CB
    HAWTHORNE, MF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (05) : 206 - 207
  • [10] MODEL INTERMEDIATES FOR RHODACARBORANE CATALYSIS - ISOLATION OF A DISUBSTITUTED CLOSO-BIS(TRIPHENYLPHOSPHINE)HYDRIDORHODACARBORANE
    HEWES, JD
    THOMPSON, M
    HAWTHORNE, MF
    [J]. ORGANOMETALLICS, 1985, 4 (01) : 13 - 17
123