Electrochemically Alternating Voltage Induced Mn3O4/Graphite Powder Composite with Enhanced Electrochemical Performances for Lithium-ion Batteries

被引:36
作者
Jing, Mingjun [1 ]
Hou, Hongshuai [1 ]
Yang, Yingchang [1 ]
Zhang, Yan [1 ]
Yang, Xuming [1 ]
Chen, Qiyuan [1 ]
Ji, Xiaobo [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Mn3O4/graphite powder composite; alternating voltage; electrochemical performances; lithium-ion batteries; CAPACITY ANODE MATERIAL; REVERSIBLE CAPACITY; FACILE PREPARATION; MN3O4; GRAPHENE; NANOPARTICLES; OCTAHEDRA; STORAGE; ROUTE; METAL;
D O I
10.1016/j.electacta.2014.12.170
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mn3O4/graphite powder (Mn3O4/GhP) composite was successfully obtained utilizing an alternating voltage induced electrochemical method. It was found that Mn3O4 particles (similar to 20 nm) resulted from Mn electrodes were well dispersed on the surface of GhP. The electrochemical performances of Mn3O4/GhP material as anode for lithium-ion batteries were investigated, demonstrating high specific capacity and excellent cycling stability with a high charge-discharge capacity of 1007.4 mAh g (1) after 50 cycles at a current density of 100mA g (1). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:157 / 163
页数:7
相关论文
共 36 条
[1]   Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity [J].
Balaya, P ;
Li, H ;
Kienle, L ;
Maier, J .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (08) :621-625
[2]   A comparative study on the nanocrystalline ZnO thin films prepared by ultrasonic spray and sol-gel method [J].
Benramache, Said ;
Benhaoua, Boubaker ;
Chabane, Foued ;
Guettaf, Abderrazak .
OPTIK, 2013, 124 (18) :3221-3224
[3]   Facile synthesis of graphene-supported mesoporous Mn3O4 nanosheets with a high-performance in Li-ion batteries [J].
Chen, Chao ;
Jian, Hong ;
Fu, Xinxin ;
Ren, Zhimin ;
Yan, Mi ;
Qian, Guodong ;
Wang, Zhiyu .
RSC ADVANCES, 2014, 4 (11) :5367-5370
[4]   A simple and generic approach for synthesizing colloidal metal and metal oxide nanocrystals [J].
Cloud, Jacqueline E. ;
Yoder, Tara S. ;
Harvey, Nathan K. ;
Snow, Kyle ;
Yang, Yongan .
NANOSCALE, 2013, 5 (16) :7368-7378
[5]   Electrochemical capacitors utilising transition metal oxides: an update of recent developments [J].
Deng, Wentao ;
Ji, Xiaobo ;
Chen, Qiyuan ;
Banks, Craig E. .
RSC ADVANCES, 2011, 1 (07) :1171-1178
[6]   A green chemical route for the synthesis of Mn3O4 nanoparticles [J].
Durmus, Zehra ;
Kavas, Hueseyin ;
Baykal, Abdulhadi ;
Toprak, Muhammet S. .
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2009, 7 (03) :555-559
[7]   Spongelike Nanosized Mn3O4 as a High-Capacity Anode Material for Rechargeable Lithium Batteries [J].
Gao, Jie ;
Lowe, Michael A. ;
Abruna, Hector D. .
CHEMISTRY OF MATERIALS, 2011, 23 (13) :3223-3227
[8]   Interdispersed Amorphous MnOx-Carbon Nanocomposites with Superior Electrochemical Performance as Lithium-Storage Material [J].
Guo, Juchen ;
Liu, Qing ;
Wang, Chunsheng ;
Zachariah, Michael R. .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (04) :803-811
[9]   Facile preparation of Mn3O4 octahedra and their long-term cycle life as an anode material for Li-ion batteries [J].
Hao, Qin ;
Wang, Jinping ;
Xu, Caixia .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (01) :87-93
[10]   Engineering single crystalline Mn3O4 nano-octahedra with exposed highly active {011} facets for high performance lithium ion batteries [J].
Huang, Shao-Zhuan ;
Jin, Jun ;
Cai, Yi ;
Li, Yu ;
Tan, Hai-Yan ;
Wang, Hong-En ;
Van Tendeloo, G. ;
Su, Bao-Lian .
NANOSCALE, 2014, 6 (12) :6819-6827