Electrochemically Alternating Voltage Induced Mn3O4/Graphite Powder Composite with Enhanced Electrochemical Performances for Lithium-ion Batteries

被引:36
作者
Jing, Mingjun [1 ]
Hou, Hongshuai [1 ]
Yang, Yingchang [1 ]
Zhang, Yan [1 ]
Yang, Xuming [1 ]
Chen, Qiyuan [1 ]
Ji, Xiaobo [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Mn3O4/graphite powder composite; alternating voltage; electrochemical performances; lithium-ion batteries; CAPACITY ANODE MATERIAL; REVERSIBLE CAPACITY; FACILE PREPARATION; MN3O4; GRAPHENE; NANOPARTICLES; OCTAHEDRA; STORAGE; ROUTE; METAL;
D O I
10.1016/j.electacta.2014.12.170
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mn3O4/graphite powder (Mn3O4/GhP) composite was successfully obtained utilizing an alternating voltage induced electrochemical method. It was found that Mn3O4 particles (similar to 20 nm) resulted from Mn electrodes were well dispersed on the surface of GhP. The electrochemical performances of Mn3O4/GhP material as anode for lithium-ion batteries were investigated, demonstrating high specific capacity and excellent cycling stability with a high charge-discharge capacity of 1007.4 mAh g (1) after 50 cycles at a current density of 100mA g (1). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:157 / 163
页数:7
相关论文
共 36 条
  • [1] Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity
    Balaya, P
    Li, H
    Kienle, L
    Maier, J
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (08) : 621 - 625
  • [2] A comparative study on the nanocrystalline ZnO thin films prepared by ultrasonic spray and sol-gel method
    Benramache, Said
    Benhaoua, Boubaker
    Chabane, Foued
    Guettaf, Abderrazak
    [J]. OPTIK, 2013, 124 (18): : 3221 - 3224
  • [3] Facile synthesis of graphene-supported mesoporous Mn3O4 nanosheets with a high-performance in Li-ion batteries
    Chen, Chao
    Jian, Hong
    Fu, Xinxin
    Ren, Zhimin
    Yan, Mi
    Qian, Guodong
    Wang, Zhiyu
    [J]. RSC ADVANCES, 2014, 4 (11) : 5367 - 5370
  • [4] A simple and generic approach for synthesizing colloidal metal and metal oxide nanocrystals
    Cloud, Jacqueline E.
    Yoder, Tara S.
    Harvey, Nathan K.
    Snow, Kyle
    Yang, Yongan
    [J]. NANOSCALE, 2013, 5 (16) : 7368 - 7378
  • [5] Electrochemical capacitors utilising transition metal oxides: an update of recent developments
    Deng, Wentao
    Ji, Xiaobo
    Chen, Qiyuan
    Banks, Craig E.
    [J]. RSC ADVANCES, 2011, 1 (07) : 1171 - 1178
  • [6] A green chemical route for the synthesis of Mn3O4 nanoparticles
    Durmus, Zehra
    Kavas, Hueseyin
    Baykal, Abdulhadi
    Toprak, Muhammet S.
    [J]. CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2009, 7 (03): : 555 - 559
  • [7] Spongelike Nanosized Mn3O4 as a High-Capacity Anode Material for Rechargeable Lithium Batteries
    Gao, Jie
    Lowe, Michael A.
    Abruna, Hector D.
    [J]. CHEMISTRY OF MATERIALS, 2011, 23 (13) : 3223 - 3227
  • [8] Interdispersed Amorphous MnOx-Carbon Nanocomposites with Superior Electrochemical Performance as Lithium-Storage Material
    Guo, Juchen
    Liu, Qing
    Wang, Chunsheng
    Zachariah, Michael R.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (04) : 803 - 811
  • [9] Facile preparation of Mn3O4 octahedra and their long-term cycle life as an anode material for Li-ion batteries
    Hao, Qin
    Wang, Jinping
    Xu, Caixia
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (01) : 87 - 93
  • [10] Engineering single crystalline Mn3O4 nano-octahedra with exposed highly active {011} facets for high performance lithium ion batteries
    Huang, Shao-Zhuan
    Jin, Jun
    Cai, Yi
    Li, Yu
    Tan, Hai-Yan
    Wang, Hong-En
    Van Tendeloo, G.
    Su, Bao-Lian
    [J]. NANOSCALE, 2014, 6 (12) : 6819 - 6827