Influence of Nanoclay on Phenol-Formaldehyde and Phenol-Urea-Formaldehyde Resins for Wood Adhesives

被引:25
|
作者
Lei, H. [1 ,2 ,3 ]
Du, G. [2 ]
Pizzi, A. [1 ]
Celzard, A. [1 ]
Fang, Q. [2 ]
机构
[1] Nancy Univ, ENSTIB, F-88051 Epinal, France
[2] SW Forestry Coll, Kunming 650224, Yunnan, Peoples R China
[3] Nanjing Forestry Univ, Nanjing 210037, Jiangsu, Peoples R China
关键词
Nanoclay; phenol-formaldehyde resins; phenol-urea-formaldehyde resins; thermosetting resins; adhesives; LAYERED SILICATE NANOCOMPOSITES; ACID-MODIFIED MONTMORILLONITE; REACTION EXFOLIATION; MELT INTERCALATION; THERMAL-STABILITY; MORPHOLOGY; HYBRID;
D O I
10.1163/016942410X500945
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The addition of small percentages of Na+-montmorillonite (NaMMT) nanoclay does not appear to improve much the performance of thermosetting phenol-formaldehyde (PF) and phenol-urea-formaldehyde (PUF) resins used as adhesives for plywood and for wood particleboard. X-ray diffraction (XRD) studies indicated that NaMMT does not become completely exfoliated when mixed in small proportions to PF resins, contrary to that observed for acid-setting urea-formaldehyde (UF) resins. Differential scanning calorimetry (DSC) indicated that NaMMT has no accelerating effect on the curing of alkaline PF resins, contrary to that observed for UF resins. (C) Koninklijke Brill NV, Leiden, 2010
引用
收藏
页码:1567 / 1576
页数:10
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