The synergistic effect of Bi2WO6 nanoplates and Co3O4 cocatalysts for enhanced photoelectrochemical properties

被引:49
作者
Dong, Guojun [1 ,2 ]
Zhang, Yajun [1 ]
Bi, Yingpu [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, AState Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
WATER; PHOTOANODES; ARRAYS; BIVO4; PHOTOCATALYST; FABRICATION; ELECTRODE; ROUTE;
D O I
10.1039/c7ta06225g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, we demonstrated the controllable fabrication of Bi2WO6 nanoplate arrays decorated with Co3O4 cocatalysts through the combination of hydrothermal reactions with annealing treatments. The synergistic effect of bulk charge transport and surface oxygen evolution could significantly improve the photoelectrochemical properties (0.45 mA cm(-2), 1.23 V-RHE) for water splitting under simulated solar light, which are much higher than those of traditional Bi2WO6 particle photoanodes (0.02 mA cm-2, 1.23 V-RHE). These demonstrations clearly reveal that the rational construction of a photoanode structure and selective decoration of oxygen evolution cocatalysts could serve as an alternative strategy toward the development of highly efficient water splitting systems.
引用
收藏
页码:20594 / 20597
页数:4
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