Nanocomposite synthesis of MoS2/nano-CeO2 for high-performance electromagnetic absorption

被引:16
作者
Chen, Hui [1 ]
Shen, Jun [1 ]
Zhang, Yanhua [2 ]
机构
[1] Chongqing Univ, Coll Mat Sci & Engn, State Key Lab Mech Transmiss, Chongqing 400044, Peoples R China
[2] Chongqing Municipal Key Lab Micro Nano Mat Engn &, Chongqing, Peoples R China
关键词
REDUCED GRAPHENE OXIDE; MICROWAVE-ABSORPTION; HYDROTHERMAL SYNTHESIS; MOS2; NANOSHEETS; COMPLEX PERMITTIVITY; CEO2; OXYGEN VACANCY; NANOCRYSTALS; PERMEABILITY; ENHANCEMENT;
D O I
10.1007/s10854-021-06755-z
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The MoS2/CeO2 composites with different contents and grain sizes CeO2 were synthesized to research the electromagnetic (EM) absorbing mechanism and properties. The as-prepared MoS2/nano-CeO2 exhibits excellent microwave absorption performance. The best reflection loss (RL) peak of MoS2/nano-CeO2 with 0.03 g nano-CeO2 reached - 56.3dB at 10.7 GHz with the matching thickness of 3 mm. Compared with MoS2/micron-CeO2 and pure MoS2, the MoS2/nano-CeO2 nanocomposite achieved wider and stronger wave absorption performance. It is found that the high content of Ce3+ in nano-CeO2 should produce a higher concentration of oxygen vacancy defects, which improved the conduction loss and dielectric loss of MoS2/nano-CeO2 nanocomposites. In addition, the multiple interface polarization between MoS2 nano-sheets and nano-CeO2 is beneficial for EM wave absorption. This work provides a new reference path for the design of EM absorption materials, especially two-dimensional (2D) materials doped with rare-earth (RE) nanoparticles. The quality of the MoS2/nano-CeO2 is smaller than traditional microwave absorption materials, which is of great significance for practical application.
引用
收藏
页码:22689 / 22698
页数:10
相关论文
共 59 条
[1]   Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].
Banfield, JF ;
Welch, SA ;
Zhang, HZ ;
Ebert, TT ;
Penn, RL .
SCIENCE, 2000, 289 (5480) :751-754
[2]   Chemistry - Oxygen vacancies and catalysis on ceria surfaces [J].
Campbell, CT ;
Peden, CHF .
SCIENCE, 2005, 309 (5735) :713-714
[3]  
Chang-Hai DU., 2006, MOD CHEM IND, V26, P119
[4]   Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes [J].
Che, RC ;
Peng, LM ;
Duan, XF ;
Chen, Q ;
Liang, XL .
ADVANCED MATERIALS, 2004, 16 (05) :401-+
[5]   Facile synthesis of hierarchical MoS2-carbon microspheres as a robust anode for lithium ion batteries [J].
Chen, Gen ;
Wang, Shengping ;
Yi, Ran ;
Tan, Longfei ;
Li, Hongbo ;
Zhou, Meng ;
Yan, Litao ;
Jiang, Yingbing ;
Tan, Shuai ;
Wang, Donghai ;
Deng, Shuguang ;
Meng, Xianwei ;
Luo, Hongmei .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (24) :9653-9660
[6]   Hierarchical MoS2/Bi2MoO6 composites with synergistic effect for enhanced visible photocatalytic activity [J].
Chen, Yajie ;
Tian, Guohui ;
Shi, Yunhan ;
Xiao, Yuting ;
Fu, Honggang .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 164 :40-47
[7]   Blockchain-Based Medical Records Secure Storage and Medical Service Framework [J].
Chen, Yi ;
Ding, Shuai ;
Xu, Zheng ;
Zheng, Handong ;
Yang, Shanlin .
JOURNAL OF MEDICAL SYSTEMS, 2019, 43 (01)
[8]   Dilute-defect magnetism: Origin of magnetism in nanocrystalline CeO2 [J].
Fernandes, V. ;
Mossanek, R. J. O. ;
Schio, P. ;
Klein, J. J. ;
de Oliveira, A. J. A. ;
Ortiz, W. A. ;
Mattoso, N. ;
Varalda, J. ;
Schreiner, W. H. ;
Abbate, M. ;
Mosca, D. H. .
PHYSICAL REVIEW B, 2009, 80 (03)
[9]   Controlled hydrothermal synthesis of triangular CeO2 nanosheets and their formation mechanism and optical properties [J].
Gong, Jinfeng ;
Meng, Fanming ;
Yang, Xin ;
Fan, Zhenghua ;
Li, Huijie .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 689 :606-616
[10]   Thermally Stable Hierarchical Nanostructures of Ultrathin MoS2 Nanosheet-Coated CeO2 Hollow Spheres as Catalyst for Ammonia Decomposition [J].
Gong, Xueyun ;
Gu, Ying-Qiu ;
Li, Na ;
Zhao, Hongyang ;
Jia, Chun-Jiang ;
Du, Yaping .
INORGANIC CHEMISTRY, 2016, 55 (08) :3992-3999