Partition constants of α-aminophosphonates in two-phase aqueous-organic solvent systems

被引：3

作者：

Garifzyanov, AR ^{[1
]}

Nuriazdanova, GK ^{[1
]}

Zakharov, SV ^{[1
]}

Cherkasov, RA ^{[1
]}

机构：

[1] Kazan VI Lenin State Univ, Kazan 420008, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2004年 / 74卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1007/s11176-005-0112-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-phase potentiometric titration was used to determine partition constants for a series of alpha-aminophosphonates (RO)(2)P(O)(CH2NRR2)-R-1 [R = Alk (C-2-C-5), R-1, R-2 = Me, Et, (CH2)(5)] between water and organic solvents, such as chloroform, carbon tetrachloride, toluene, octane, n-octanol, nitrobenzerie, o-xylene, and cyclohexane. Correlations between the partition constants and the number of carbon atoms in substrate molecules were obtained. Solvent effects on partition constants were discussed, and solution parameters of alpha-aminophosphonates were calculated.

引用

页码：1885 / 1889

页数：5

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