Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers

被引：81

作者：

Belen Marco, A. ^{[1
]}

Cortizo-Lacalle, Diego ^{[1
]}

Perez-Miqueo, Inigo ^{[3
]}

Valenti, Giovanni ^{[4
]}

Boni, Alessandro ^{[4
]}

Plas, Jan ^{[5
]}

Strutynski, Karol ^{[7
]}

De Feyter, Steven ^{[5
]}

Paolucci, Francesco ^{[4
]}

Montes, Mario ^{[3
]}

Khlobystov, Andrei N. ^{[6
]}

Melle-Franco, Manuel ^{[7
]}

Mateo-Alonso, Aurelio ^{[1
,2
]}

机构：

[1] Univ Basque Country UPV EHU, POLYMAT, Ave Tolosa 72, Donostia San Sebastian 20018, Spain

[2] Basque Fdn Sci, Ikerbasque, Bilbao 48011, Spain

[3] Univ Basque Country, Fac C Quim, Dept Quim Aplicada, Grp Ingn Quim, Apdo 1072, San Sebastian 20080, Spain

[4] Dipartimento Chim Giacomo Ciamician, Via Selmi 2, I-40126 Bologna, Italy

[5] Katholieke Univ Leuven, Dept Chem, Div Mol Imaging & Photon, Celestijnenlaan 200F, B-3001 Leuven, Belgium

[6] Univ Nottingham, Sch Chem, Univ Pk, Nottingham, England

[7] Univ Aveiro, Dept Chem, CICECO, Aveiro Inst Mat, P-3810193 Aveiro, Portugal

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 24期

关键词：

carbon nanostructures; materials science; nanocarbons; organic frameworks; twisted aromatic systems; COVALENT ORGANIC FRAMEWORKS; METAL-FREE ELECTROCATALYSTS; OXYGEN REDUCTION; HYDROGEN EVOLUTION; GRAPHENE; CARBON; NANOSHEETS; CHEMISTRY; FUNCTIONALIZATION; DELAMINATION;

D O I：

10.1002/anie.201700271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.

引用

页码：6946 / 6951

页数：6

共 56 条

[41] Bifunctional Metal-Free Catalysis of Mesoporous Noble Carbons for Oxygen Reduction and Evolution Reactions [J].

Sakaushi, Ken ;

Fellinger, Tim-Patrick ;

Antonietti, Markus .

CHEMSUSCHEM, 2015, 8 (07) :1156-1160

[42] Characterization of high-surface area electrocatalysts using a rotating disk electrode configuration [J].

Schmidt, TJ ;

Gasteiger, HA ;

Stab, GD ;

Urban, PM ;

Kolb, DM ;

Behm, RJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (07) :2354-2358

[43] Covalent organic frameworks based on Schiff-base chemistry: synthesis, properties and potential applications [J].

Segura, Jose L. ;

Mancheno, Maria J. ;

Zamora, Felix .

CHEMICAL SOCIETY REVIEWS, 2016, 45 (20) :5635-5671

[44] OPTICAL PROPERTIES AND ELECTRONIC STRUCTURE OF AMORPHOUS [J].

TAUC, J .

MATERIALS RESEARCH BULLETIN, 1968, 3 (01) :37-&

[45] Virtually pure near-infrared electroluminescence from exciplexes at polyfluorene/hexaazatrinaphthylene interfaces [J].

Tregnago, G. ;

Flechon, C. ;

Choudhary, S. ;

Gozalvez, C. ;

Mateo-Alonso, A. ;

Cacialli, F. .

APPLIED PHYSICS LETTERS, 2014, 105 (14)

[46] Non-conventional methods and media for the activation and manipulation of carbon nanoforms [J].

Vazquez, Ester ;

Giacalone, Francesco ;

Prato, Maurizio .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (01) :58-69

[47] Chemistry of Covalent Organic Frameworks [J].

Waller, Peter J. ;

Gandara, Felipe ;

Yaghi, Omar M. .

ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (12) :3053-3063

[48] Well-defined two dimensional covalent organic polymers: rational design, controlled syntheses, and potential applications [J].

Xiang, Zhonghua ;

Cao, Dapeng ;

Dai, Liming .

POLYMER CHEMISTRY, 2015, 6 (11) :1896-1911

[49] Nitrogen-Doped Holey Graphitic Carbon from 2D Covalent Organic Polymers for Oxygen Reduction [J].

Xiang, Zhonghua ;

Cao, Dapeng ;

Huang, Ling ;

Shui, Jianglan ;

Wang, Min ;

Dai, Liming .

ADVANCED MATERIALS, 2014, 26 (20) :3315-+

[50] Highly Efficient Electrocatalysts for Oxygen Reduction Based on 2D Covalent Organic Polymers Complexed with Non-precious Metals [J].

Xiang, Zhonghua ;

Xue, Yuhua ;

Cao, Dapeng ;

Huang, Ling ;

Chen, Jian-Feng ;

Dai, Liming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (09) :2433-2437

← 1 2 3 4 5 6 →