Synthesis and Thermal Conversions of Unsaturated Nickel(II) Dicarboxylates as Precursors of Metallopolymer Nanocomposites

被引：9
作者：
Musatova, V. Yu. [1 ]
Semenov, S. A. [1 ]
Drobot, D. V. [1 ]
Pronin, A. S. [1 ]
Pomogailo, A. D. [2 ]
Dzhardimalieva, G. I. [2 ]
Popenko, V. I. [3 ]
机构：
[1] Moscow Technol Univ, Inst Fine Chem Technol, Pr Vernadskogo 86, Moscow 119571, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Pr Akad Semenova 1, Chernogolovka 142432, Moscow Oblast, Russia
[3] Russian Acad Sci, Engelhardt Inst Mol Biol, Ul Vavilova 32, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 61卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
SOL-GEL SYNTHESIS; MAGNETIC-PROPERTIES; NANOPARTICLES; CARBON; SENSITIVITY; COBALT(II); ELECTRODE; FILMS; ACID; IRON;
D O I：
10.1134/S0036023616090163
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Nickel(II) dicarboxylates of unsaturated carboxylic acids (maleic (MalA), itaconic (ItA), acetylenedicarboxylic (ADCA), allylmalonic (AlMalA), glutaconic (GlutA), cis,cis-muconic (MucA) acids) were synthesized and characterized by thermal analysis and IR spectroscopy. The synthesized dicarboxylates were subjected to thermolysis, and the obtained nanocomposites were studied by transmission and scanning electron microscopy and X-ray diffraction. The synthesized metallopolymer nanocomposites were NiO and metallic Ni nanoparticles distributed over a stabilizing matrix. The formation enthalpy of dicarboxylates (Delta H-r degrees) was calculated by the PM3 semi-empirical quantum-chemical method. The nanoparticle size was determined, and a relationship between the average nanoparticle diameter (d(avg)) and Delta H-r degrees was established. The microstructure and magnetic characteristics of the obtained nanocomposites, namely, the maximum and residual magnetization and the coercive force, were studied.
引用
收藏
页码：1111 / 1124
页数：14
相关论文
共 43 条
  • [1] Synthesis and Thermal Conversions of Unsaturated Cobalt(II) Dicarboxylates as Precursors of Metallopolymer Nanocomposites
    Semenov, S. A.
    Drobot, D. V.
    Musatova, V. Yu.
    Pronin, A. S.
    Pomogailo, A. D.
    Dzhardimalieva, G. I.
    Popenko, V. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2015, 60 (08) : 897 - 905
  • [2] Synthesis and Thermal Conversions of Unsaturated Nickel(II) Monocarboxylates-Precursors of Metal-Containing Nanocomposites
    Pronin, A. S.
    Semenov, S. A.
    Drobot, D. V.
    Volchkova, E. V.
    Dzhardimalieva, G. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (08) : 1173 - 1185
  • [3] Synthesis and Thermal Conversions of Unsaturated Cobalt(II) Monocarboxylates: Precursors for Metal Polymer Nanocomposites
    Pronin, A. S.
    Semenov, S. A.
    Drobot, D., V
    Dzhardimalieva, G., I
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (08) : 1041 - 1049
  • [4] Thermal Decomposition of Unsaturated Nickel(II) Dicarboxylates
    Semenov, S. A.
    Musatova, V. Yu.
    Drobot, D. V.
    Dzhardimalieva, G. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (09) : 1217 - 1224
  • [5] Synthesis and Thermal Transformations of Nickel(II) Salts of Saturated Monocarboxylic Acid-Precursors of Metal-Containing Nanocomposites
    Saprykin, R., V
    Semenov, S. A.
    Drobot, D., V
    Volchkova, E. V.
    Dzhardimalieva, G., I
    Ivanova, A. I.
    Golovanov, A. B.
    Popenko, V., I
    NANOBIOTECHNOLOGY REPORTS, 2022, 17 (03) : 345 - 355
  • [6] Synthesis of nanocrystalline nickel ferrite by thermal decomposition of organic precursors
    Stoia, Marcela
    Barvinschi, Paul
    Tudoran, Lucian Barbu
    Barbu, Mirela
    Stefanescu, Mircea
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 108 (03) : 1033 - 1039
  • [7] Synthesis of nanocrystalline nickel ferrite by thermal decomposition of organic precursors
    Marcela Stoia
    Paul Barvinschi
    Lucian Barbu Tudoran
    Mirela Barbu
    Mircea Stefanescu
    Journal of Thermal Analysis and Calorimetry, 2012, 108 : 1033 - 1039
  • [8] Synthesis and Characterization of Zinc(II) Oxide Nanoparticles by Thermal Decomposition of Two Zinc(II) Nitrite Coordination Polymer Precursors
    Aghabeygi, Shokufeh
    Bigdeli, Fahime
    Morsali, Ali
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2012, 22 (02) : 526 - 529
  • [9] Hydroxybenzoate salts of cobalt(II), manganese(II), and nickel(II): synthesis, crystal structure, Hirshfeld surface analyses, and thermal behavior
    Santana, Francielli Sousa
    Ramos de Lima, Bruno
    Mariano Iwaya, Eduardo
    Ferraro Miorim, Avany Judith
    Baptistella, Gabriel Barros
    Lemos de Sa, Eduardo
    Gioppo Nunes, Giovana
    Mey Reis, Dayane
    JOURNAL OF COORDINATION CHEMISTRY, 2023, 76 (5-6) : 612 - 631
  • [10] Two Manganese(II) and Zinc(II) Coordination Polymers Constructed From Imidazole Dicarboxylates: Synthesis, Crystal Structures, and Thermal Properties
    Cao, Xinjiang
    Yang, Zeli
    Guo, Mengwei
    Wang, Chengjie
    Li, Gang
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (03) : 402 - 407
12345