Pd(II)-catalyzed intramolecular C-H activation/C-C cross coupling for the synthesis of carbazoles from diaryl acetamides

被引：20

作者：

Wang, Sichang ^{[1
]}

Mao, Hui ^{[1
]}

Ni, Zhangqin ^{[1
]}

Pan, Yuanjiang ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 05期

关键词：

Palladium; C-H activation; C-C coupling; Carbazoles; CARBON-HYDROGEN BONDS; LIGHT-EMITTING-DIODES; METAL-COMPLEXES; HOST MATERIALS; ORGANIC-SYNTHESIS; FUNCTIONALIZATION; ALKALOIDS; DERIVATIVES; MOLECULES; SIAMENOL;

D O I：

10.1016/j.tetlet.2011.11.082

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pd(II)-catalyzed intramolecular C-H activation/C-C cross coupling within N,N-diphenyl-acetamides allows the efficient formation of differently substituted carbazoles. In this cross-dehydrogenative coupling, many different functional groups are tolerated and the starting material N,N-diphenyl-acetamides can be easily prepared in one step from commercially available acetanilides and iodobenzenes. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：505 / 508

页数：4

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