A Novel Molecular Cubic Perovskite Built From Charge-Assisted Hydrogen Bond Linkages

被引：23
|
作者：
Liu, Guang-Zhen [1 ]
Zhang, Jun [1 ]
Wang, Li-Ya [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 09期
基金：
中国国家自然科学基金;
关键词：
crystal structure; hydrogen bonding; hydrothermal synthesis; molecular perovskite;
D O I：
10.1080/15533174.2011.591351
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel molecular cubic perovskite (C6H14N2)(NH4)[BF4](3), space group Pa-3 (number 205), has been hydrothermally synthesized and further characterized by x-ray diffraction studies, elemental analysis, infrared spectrum, and thermogravimetric analysis. This is the Gfirst molecular cubic perovskite based on the three-dimensional (3-D) array of complex C6H14N22+ (C6H14N2 = doubly protonated 1,4-diazabicyclo[2.2.2]octane), NH4+, and BF4- modular groups that are held together largely by the extensive hydrogen bonding. This work demonstrates that the perovskite-type structure is highly flexible to diverse chemical components and can be stabilized by a wide range of chemical interactions.
引用
收藏
页码：1091 / 1094
页数：4
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