1,4-Diazabicyclo[2.2.2]octane-Promoted Addition Reaction of Tricarbonyl Monohydrates with Active Alkynes via Consecutive C-C/C-O Cleavage

被引：0

作者：

Zhang, Jinfeng ^{[1
]}

Ye, Ruyi ^{[1
]}

Li, Ziyang ^{[1
]}

Meng, Lingguo ^{[1
]}

机构：

[1] Huaibei Normal Univ, Sch Chem & Mat Sci, Huaibei 235000, Anhui, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 41卷 / 11期

关键词：

C-C cleavage; C-O cleavage; addition; promoter; BOND-CLEAVAGE; TERMINAL ALKYNOATES; CARBOXYLATE; CYCLIZATION; AZIRIDINES; COMPLEXES; CATALYSIS; ACIDS;

D O I：

10.6023/cjoc202104016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel addition reaction of vicinal tricarbonyl monohydrates with active alkynes proceeded via rapid consecutive C-C/C-O cleavage processes under metal-free and mild reaction conditions, and the transformation was completed within only 1 min. Diverse tricarbonyl monohydrates could react with active alkynes to produce carboxylate esters via these transformations in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO).

引用

页码：4384 / 4390

页数：7

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