Dynamic viscosity and speed of sound of the ternary mixture methyl acetate plus methanol plus ethanol at 298.15 K

被引:24
作者
Canosa, J [1 ]
Rodriguez, A [1 ]
Tojo, J [1 ]
机构
[1] Univ Vigo, Dept Ingn Quim, Vigo 36200, Spain
关键词
D O I
10.1021/je980076z
中图分类号
O414.1 [热力学];
学科分类号
摘要
Dynamic viscosity and speed of sound of the ternary mixture (methyl acetate + methanol + ethanol) at 298.15 K and atmospheric pressure have been measured over the whole range of mixture compositions. Viscosity deviations and deviation in isentropic compressibility for the ternary system were calculated and fitted to Cibulka's equation to estimate the fitting parameters and the root-mean-square deviations between calculated and experimental data. To correlate viscosities of the ternary system from binary data, different equations have been used and theirs parameters are shown. To predict the viscosity of the ternary mixture, several methods have been proposed; some of them are based on contribution groups, and the other ones use the binary correlation parameters. Some methods that predict viscosity deviations by means of binary contributions have been applied, and their root-mean-square deviations are presented.
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页码:961 / 966
页数:6
相关论文
共 26 条
[1]   Densities, refractive indices, speeds of sound, and isentropic compressibilities of water plus methanol plus 2-methoxy-2-methylbutane at 298.15 K [J].
Arce, A ;
MartinezAgeitos, J ;
Mendoza, J ;
Soto, A .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (04) :724-727
[2]  
Bevington R., 1969, DATA REDUCTION ERROR
[3]   Densities, refractive indices, and derived excess properties of the system methyl acetate plus methanol plus 2-butanol at 298.15 K [J].
Canosa, J ;
Rodriguez, A ;
Orge, B ;
Iglesias, M ;
Tojo, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (06) :1121-1125
[4]   Dynamic viscosities of (methyl acetate or methanol) with (ethanol, 1-propanol, 2-propanol, 1-butanol, and 2-butanol) at 298.15K [J].
Canosa, J ;
Rodriguez, A ;
Tojo, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (03) :417-421
[5]   Densities, refractive indices, and derived excess properties of {x(1)CH(3)COOCH(3)+x(2)CH(3)OH+(1-x(1)-x(2))CH3CH(OH)CE3} at the temperature 298.15 K [J].
Canosa, JM ;
Rodriguez, A ;
Iglesias, M ;
Orge, B ;
Tojo, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (08) :907-920
[6]   SIMULTANEOUS CORRELATION OF VISCOSITY AND VAPOR-LIQUID-EQUILIBRIUM DATA [J].
CAO, WH ;
KNUDSEN, K ;
FREDENSLUND, A ;
RASMUSSEN, P .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (09) :2077-2087
[7]   GROUP-CONTRIBUTION VISCOSITY PREDICTIONS OF LIQUID-MIXTURES USING UNIFAC-VLE PARAMETERS [J].
CAO, WH ;
KNUDSEN, K ;
FREDENSLUND, A ;
RASMUSSEN, P .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (09) :2088-2092
[9]  
Frenkel Y.I., 1946, KINETIC THEORY LIQUI
[10]   UNIFAC VISCO GROUP-CONTRIBUTION METHOD FOR PREDICTING KINEMATIC VISCOSITY - EXTENSION AND TEMPERATURE-DEPENDENCE [J].
GASTONBONHOMME, Y ;
PETRINO, P ;
CHEVALIER, JL .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (11) :1799-1806